{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T03:07:34Z","timestamp":1778814454152,"version":"3.51.4"},"reference-count":33,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2018,4,6]],"date-time":"2018-04-06T00:00:00Z","timestamp":1522972800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2018,4,6]],"date-time":"2018-04-06T00:00:00Z","timestamp":1522972800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/501100003093","name":"Ministry of Higher Education, Malaysia","doi-asserted-by":"publisher","award":["FRGS\/2\/2013\/SKK10\/UKM\/02\/1"],"award-info":[{"award-number":["FRGS\/2\/2013\/SKK10\/UKM\/02\/1"]}],"id":[{"id":"10.13039\/501100003093","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2018,5,1]]},"abstract":"<jats:p>The crystal and molecular structures of two triphenyltin dithiocarbamate compounds,<jats:italic>viz<\/jats:italic>. [Sn(C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub>(C<jats:sub>8<\/jats:sub>H<jats:sub>16<\/jats:sub>NS<jats:sub>2<\/jats:sub>)], (I), and [Sn(C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub>(C<jats:sub>10<\/jats:sub>H<jats:sub>12<\/jats:sub>NS<jats:sub>2<\/jats:sub>)], (II), are described. The dithiocarbamate ligand in each molecule coordinates in an asymmetric fashion resulting in heavily distorted tetrahedral C<jats:sub>3<\/jats:sub>S coordination geometries for the Sn atoms, with the distortions traced to the close approach of the non-coordinating thione-S atom. The molecular packing in both compounds features C\u2014H...\u03c0(Sn-phenyl) interactions. In (I), the donors are Sn-phenyl-C\u2014H groups leading to centrosymmetric aggregates, while in (II), the donors are both Sn-phenyl-C\u2014H and methyl-C\u2014H groups leading to supramolecular chains propagating along the<jats:italic>b<\/jats:italic>axis. The identified aggregates assemble into their respective crystals with no directional interactions between them. An analysis of the Hirshfeld surfaces show distinctive patterns, but an overwhelming predominance (&gt;99% in each case) of H...H, C...H\/H...C and S...H\/H...S contacts on the respective Hirshfeld surface.<\/jats:p>","DOI":"10.1107\/s2056989018005133","type":"journal-article","created":{"date-parts":[[2018,4,6]],"date-time":"2018-04-06T10:05:21Z","timestamp":1523009121000},"page":"630-637","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["Crystal structures and Hirshfeld surface analyses of (<i>N<\/i>-hexyl-<i>N<\/i>-methyldithiocarbamato-\u03ba<sup>2<\/sup><i>S<\/i>,<i>S<\/i>\u2032)triphenyltin(IV) and [<i>N<\/i>-methyl-<i>N<\/i>-(2-phenylethyl)dithiocarbamato-\u03ba<sup>2<\/sup><i>S<\/i>,<i>S<\/i>\u2032]triphenyltin(IV)"],"prefix":"10.1107","volume":"74","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2237-4161","authenticated-orcid":true,"given":"Rapidah","family":"Mohamad","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3772-2088","authenticated-orcid":true,"given":"Normah","family":"Awang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nurul Farahana","family":"Kamaludin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mukesh M.","family":"Jotani","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1401-1520","authenticated-orcid":true,"given":"Edward R. 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