{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:16:13Z","timestamp":1736831773289,"version":"3.33.0"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2018,7,17]],"date-time":"2018-07-17T00:00:00Z","timestamp":1531785600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2018,7,17]],"date-time":"2018-07-17T00:00:00Z","timestamp":1531785600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/501100002592","name":"Kumoh National Institute of Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002592","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2018,8,1]]},"abstract":"<jats:p>The asymmetric unit of the solvated title complex, [Ir(C<jats:sub>11<\/jats:sub>H<jats:sub>8<\/jats:sub>N)<jats:sub>2<\/jats:sub>(C<jats:sub>15<\/jats:sub>H<jats:sub>14<\/jats:sub>NO<jats:sub>3<\/jats:sub>)]\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, consists of two complex molecules together with four dichloromethane solvent molecules, one of which is disordered. In each complex molecule, the Ir<jats:sup>III<\/jats:sup> ion has a distorted octahedral coordination environment defined by two 2-phenylpyridine ligands, through two phenyl C and two pyridine N atoms, and by one <jats:italic>N<\/jats:italic>,<jats:italic>O<\/jats:italic>-bidentate 2-[(2,4-dimethoxyphenylimino)methyl]phenolate anion. The Ir<jats:sup>III<\/jats:sup> ions lie almost in the equatorial planes with deviations of 0.0396\u2005(17) and 0.0237\u2005(17)\u2005\u00c5, respectively, for the two complex molecules. In both complex molecules, the two 2-phenylpyridine ligands are nearly perpendicular to each other [dihedral angles between the least-squares-planes of 89.91\u2005(11) and 85.13\u2005(11)\u00b0]. In the crystal, intermolecular C\u2014H...O interactions as well as intermolecular C\u2014H...\u03c0 interactions are present, leading to a three-dimensional network structure. One of the four dichlormethane solvent molecules shows disorder over two sets of sites [occupancy ratio 0.79\u2005(2):0.21\u2005(2)].<\/jats:p>","DOI":"10.1107\/s2056989018009970","type":"journal-article","created":{"date-parts":[[2018,7,17]],"date-time":"2018-07-17T09:09:26Z","timestamp":1531818566000},"page":"1107-1110","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of {(<i>E<\/i>)-2-[(3,4-dimethoxyphenylimino)methyl]phenolato-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>,<i>O<\/i>\n                  <sup>1<\/sup>}bis[2-(pyridin-2-yl)phenyl-\u03ba<sup>2<\/sup>\n                  <i>C<\/i>\n                  <sup>1<\/sup>,<i>N<\/i>]iridium(III) dichloromethane disolvate"],"prefix":"10.1107","volume":"74","author":[{"given":"Nirmal K.","family":"Shee","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chang Seop","family":"Hong","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Woo Ram","family":"Lee","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hee-Joon","family":"Kim","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,7,17]]},"reference":[{"key":"wm5449_bb1","doi-asserted-by":"crossref","first-page":"5642","DOI":"10.1039\/C6RA24792J","volume":"7","author":"Alam","year":"2017","journal-title":"RSC Adv."},{"key":"wm5449_bb2","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1107\/S2053273314022207","volume":"71","author":"Bourhis","year":"2015","journal-title":"Acta Cryst. 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