{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,25]],"date-time":"2025-10-25T12:28:08Z","timestamp":1761395288406,"version":"3.37.3"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2018,7,27]],"date-time":"2018-07-27T00:00:00Z","timestamp":1532649600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2018,7,27]],"date-time":"2018-07-27T00:00:00Z","timestamp":1532649600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"funder":[{"DOI":"10.13039\/100013010","name":"Universit\u00e9 Mohammed V de Rabat","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100013010","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2018,8,1]]},"abstract":"<jats:p>The title compound, Ag<jats:sub>2<\/jats:sub>Zn<jats:sub>2<\/jats:sub>Fe(VO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>, has been synthesized by solid-state reactions and belongs to the alluaudite structure family. In the crystal structure, four sites are positioned at special positions. One silver site is located on an inversion centre (Wyckoff position 4<jats:italic>b<\/jats:italic>), and an additional silver site, as well as one zinc and one vanadium site, on twofold rotation axes (4<jats:italic>e<\/jats:italic>). One site on a general position is statistically occupied by Fe<jats:sup>III<\/jats:sup> and Zn<jats:sup>II<\/jats:sup> cations that are octahedrally surrounded by O atoms. The three-dimensional framework structure of the title vanadate results from [(Zn,Fe)<jats:sub>2<\/jats:sub>O<jats:sub>10<\/jats:sub>] units of edge-sharing [(Zn,Fe)O<jats:sub>6<\/jats:sub>] octahedra that alternate with [ZnO<jats:sub>6<\/jats:sub>] octahedra so as to form infinite chains parallel to [10\\overline{1}]. These chains are linked through VO<jats:sub>4<\/jats:sub> tetrahedra by sharing vertices, giving rise to layers extending parallel to (010). Such layers are shared by common vanadate tetrahedra. The resulting three-dimensional framework delimits two types of channels parallel to [001] in which the silver sites are located with four- and sixfold coordination by oxygen.<\/jats:p>","DOI":"10.1107\/s205698901801071x","type":"journal-article","created":{"date-parts":[[2018,7,26]],"date-time":"2018-07-26T14:48:41Z","timestamp":1532616521000},"page":"1155-1158","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure of disilver(I) dizinc(II) iron(III) tris(orthovanadate) with an alluaudite-type structure"],"prefix":"10.1107","volume":"74","author":[{"given":"Nour El Houda","family":"Lamsakhar","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mohammed","family":"Zriouil","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Abderrazzak","family":"Assani","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mohamed","family":"Saadi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7980-974X","authenticated-orcid":true,"given":"Lahcen","family":"El Ammari","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,7,27]]},"reference":[{"key":"wm5454_bb1","doi-asserted-by":"crossref","first-page":"220","DOI":"10.1107\/S2056989016000931","volume":"72","author":"Benhsina","year":"2016","journal-title":"Acta Cryst. 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