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Each Cu<jats:sup>2+<\/jats:sup>cation is further coordinated by the N atoms of a bidentate ethyl (1,10-phenanthrolin-3-yl)phosphonate anion and a water molecule in a square-pyramidal geometry. In the crystal, a network of O\u2014H...O hydrogen bonds involving the P(O)(O<jats:sup>\u2212<\/jats:sup>)(OEt) groups, bridging hydroxyl groups, coordinated and uncoordinated water molecules generates a three-dimensional supramolecular structure. 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