{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,21]],"date-time":"2025-09-21T18:04:28Z","timestamp":1758477868257,"version":"3.33.0"},"reference-count":17,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2019,1,4]],"date-time":"2019-01-04T00:00:00Z","timestamp":1546560000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,1,4]],"date-time":"2019-01-04T00:00:00Z","timestamp":1546560000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["2017R1C1B2003111"],"award-info":[{"award-number":["2017R1C1B2003111"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Ministry of Science and Information Communications Technology"},{"DOI":"10.13039\/501100002541","name":"Pohang University of Science and Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002541","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2018,12,27]]},"published-print":{"date-parts":[[2019,2,1]]},"abstract":"<jats:p>The title compound, [Cu(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>10<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>2<\/jats:sub>O)], has been synthesized and characterized by synchrotron single-crystal diffraction at 100\u2005K. The Cu<jats:sup>II<\/jats:sup> ion has a distorted square-pyramidal coordination geometry with two N and one O atoms of the C<jats:sub>10<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>2<\/jats:sub>O ligand and one nitrate anion in the equatorial plane and another nitrate anion at the axial position. The equatorial Cu\u2014N and Cu\u2014O bond lengths are in the range 1.9608\u2005(14)\u20132.0861\u2005(15)\u2005\u00c5, which are shorter than the axial Cu\u2014O<jats:sub>nitrate<\/jats:sub> bond length [2.1259\u2005(16)\u2005\u00c5]. In the crystal, molecules are linked <jats:italic>via<\/jats:italic> intermolecular N\u2014H...O and O\u2014H...O hydrogen bonds, forming a sheet structure parallel to the <jats:italic>bc<\/jats:italic> plane. The sheets are further linked through a face-to-face \u03c0\u2013\u03c0 interaction [centroid\u2013centroid distance = 3.994\u2005(1)\u2005\u00c5]. Weak intermolecular C\u2014H...O interactions are also observed in the sheet and between adjacent sheets.<\/jats:p>","DOI":"10.1107\/s2056989018018352","type":"journal-article","created":{"date-parts":[[2019,1,4]],"date-time":"2019-01-04T09:06:00Z","timestamp":1546592760000},"page":"150-153","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of {2-methyl-2-[(pyridin-2-ylmethyl)amino]propan-1-ol-\u03ba<sup>3<\/sup>\n                  <i>N<\/i>,<i>N<\/i>\u2032,<i>O<\/i>}bis(nitrato-\u03ba<i>O<\/i>)copper(II) from synchrotron data"],"prefix":"10.1107","volume":"75","author":[{"given":"Jong Won","family":"Shin","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dae-Woong","family":"Kim","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jae-Woo","family":"Jeon","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dohyun","family":"Moon","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,1,4]]},"reference":[{"key":"is5504_bb1","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/j.poly.2017.01.050","volume":"127","author":"Ahn","year":"2017","journal-title":"Polyhedron"},{"key":"is5504_bb2","doi-asserted-by":"crossref","first-page":"13159","DOI":"10.1039\/C4DT01098A","volume":"43","author":"Chia","year":"2014","journal-title":"Dalton Trans."},{"key":"is5504_bb3","doi-asserted-by":"crossref","first-page":"469","DOI":"10.1002\/ejic.201700977","author":"El-Khatib","year":"2018","journal-title":"Eur. 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