{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T11:07:28Z","timestamp":1776337648786,"version":"3.51.2"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2019,2,8]],"date-time":"2019-02-08T00:00:00Z","timestamp":1549584000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,2,8]],"date-time":"2019-02-08T00:00:00Z","timestamp":1549584000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,1,28]]},"published-print":{"date-parts":[[2019,3,1]]},"abstract":"<jats:p>In the centrosymmetric (racemic) title compound, chlorido(3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one-\u03ba<jats:italic>O<\/jats:italic>)triphenyltin(IV), [Sn(C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub>Cl(C<jats:sub>15<\/jats:sub>H<jats:sub>19<\/jats:sub>NOS)], the tin(IV) atom exhibits a trigonal\u2013bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O\u2014Sn\u2014Cl = 175.07\u2005(14)\u00b0]. The thiazolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3\u2005(9)\u00b0 with respect to the pendant <jats:italic>C<\/jats:italic>-phenyl plane and 34.3\u2005(11)\u00b0 to the <jats:italic>N<\/jats:italic>-cyclohexyl ring (all atoms). The <jats:italic>C<\/jats:italic>-phenyl and <jats:italic>N<\/jats:italic>-cyclohexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1\u2005(4)\u00b0 between them. In the crystal, molecules are linked by weak C\u2014H...Cl hydrogen bonds to generate [001] chains.<\/jats:p>","DOI":"10.1107\/s2056989019001592","type":"journal-article","created":{"date-parts":[[2019,2,8]],"date-time":"2019-02-08T13:35:01Z","timestamp":1549632901000},"page":"338-341","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazolidin-4-one"],"prefix":"10.1107","volume":"75","author":[{"given":"Hemant P.","family":"Yennawar","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"John","family":"Tierney","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1815-779X","authenticated-orcid":true,"given":"Kevin C.","family":"Cannon","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,2,8]]},"reference":[{"key":"hb7780_bb1","unstructured":"Beraldo, H. & de Lima, G. 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