{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,5,13]],"date-time":"2025-05-13T08:06:29Z","timestamp":1747123589804,"version":"3.37.3"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2019,3,7]],"date-time":"2019-03-07T00:00:00Z","timestamp":1551916800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,3,7]],"date-time":"2019-03-07T00:00:00Z","timestamp":1551916800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100002441","name":"Andong National University","doi-asserted-by":"publisher","award":["2018 Research Fund"],"award-info":[{"award-number":["2018 Research Fund"]}],"id":[{"id":"10.13039\/501100002441","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004083","name":"Ministry of Science ICT and Future Planning","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004083","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002541","name":"Pohang University of Science and Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002541","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,2,28]]},"published-print":{"date-parts":[[2019,4,1]]},"abstract":"<jats:p>The structure of the title compound, [Cr(tacn)<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub>[ZnCl<jats:sub>4<\/jats:sub>]<jats:sub>3<\/jats:sub>\u00b7H<jats:sub>2<\/jats:sub>O (tacn is 1,4,7-triazacyclononane; C<jats:sub>6<\/jats:sub>H<jats:sub>15<\/jats:sub>N<jats:sub>3<\/jats:sub>), has been determined from synchrotron X-ray data. Each Cr<jats:sup>III<\/jats:sup>cation is coordinated by the six N atoms from the two tacn ligands, displaying a distorted octahedral geometry. Three distorted tetrahedral [ZnCl<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>anions and one lattice water molecule lie outside this coordination sphere. The Cr\u2014N bond lengths are in the range 2.0621\u2005(11) to 2.0851\u2005(12)\u2005\u00c5, while the mean inner N\u2014Cr\u2014N bond angle is 82.51\u2005(5)\u00b0. The crystal packing is stabilized by hydrogen-bonding interactions with the N\u2014H groups of the tacn ligands and the water O\u2014H groups acting as donors, and the O atoms of the water molecules and Cl atoms of the [ZnCl<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>anions as acceptors. Overall these contacts lead to the formation of a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s2056989019003086","type":"journal-article","created":{"date-parts":[[2019,3,11]],"date-time":"2019-03-11T13:19:47Z","timestamp":1552310387000},"page":"428-431","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structure of bis[bis(1,4,7-triazacyclononane-\u03ba<sup>3<\/sup><i>N<\/i>,<i>N<\/i>\u2032,<i>N<\/i>\u2032\u2032)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data"],"prefix":"10.1107","volume":"75","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6903-0270","authenticated-orcid":true,"given":"Dohyun","family":"Moon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5109-771X","authenticated-orcid":true,"given":"Jong-Ha","family":"Choi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,3,7]]},"reference":[{"key":"sj5569_bb1","doi-asserted-by":"crossref","first-page":"1452","DOI":"10.1039\/C39880001452","author":"Blake","year":"1988","journal-title":"J. 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