{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:48:50Z","timestamp":1740174530090,"version":"3.37.3"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2019,4,2]],"date-time":"2019-04-02T00:00:00Z","timestamp":1554163200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,4,2]],"date-time":"2019-04-02T00:00:00Z","timestamp":1554163200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,3,20]]},"published-print":{"date-parts":[[2019,5,1]]},"abstract":"<jats:p>The asymmetric unit of the title compound,<jats:italic>trans<\/jats:italic>-diaqua(3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane-\u03ba<jats:sup>4<\/jats:sup><jats:italic>N<\/jats:italic><jats:sup>1<\/jats:sup>,<jats:italic>N<\/jats:italic><jats:sup>5<\/jats:sup>,<jats:italic>N<\/jats:italic><jats:sup>8<\/jats:sup>,<jats:italic>N<\/jats:italic><jats:sup>12<\/jats:sup>)copper(II) 4,4\u2032-methylenebis(3-hydroxynaphthalene-2-carboxylate), [Cu(C<jats:sub>10<\/jats:sub>H<jats:sub>26<\/jats:sub>N<jats:sub>6<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>](C<jats:sub>23<\/jats:sub>H<jats:sub>14<\/jats:sub>O<jats:sub>6<\/jats:sub>) {[Cu(<jats:italic>L<\/jats:italic>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>](pam), where<jats:italic>L<\/jats:italic>= 3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane and pam = dianion of pamoic acid} consists of two independent halves of the [Cu(<jats:italic>L<\/jats:italic>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]<jats:sup>2+<\/jats:sup>cation and one dicarboxylate anion. The Cu<jats:sup>II<\/jats:sup>atoms, lying on inversion centres, are coordinated by the four secondary N atoms of the macrocyclic ligands and the mutually<jats:italic>trans<\/jats:italic>O atoms of the water molecules in a tetragonally elongated octahedral geometry. The average equatorial Cu\u2014N bond length is significantly shorter than the average axial Cu\u2014O bond length [2.007\u2005(10) and 2.486\u2005(18)\u2005\u00c5, respectively]. The macrocyclic ligand in the complex cations adopts the most energetically stable<jats:italic>trans<\/jats:italic>-III conformation. The complex cations and anions are connected<jats:italic>via<\/jats:italic>hydrogen-bonding interactions between the N\u2014H groups of the macrocycles and the O\u2014H groups of coordinated water molecules as the proton donors and the O atoms of the carboxylate as the proton acceptors into layers lying parallel to the (1\\overline{1}1) plane.<\/jats:p>","DOI":"10.1107\/s2056989019003852","type":"journal-article","created":{"date-parts":[[2019,4,2]],"date-time":"2019-04-02T08:39:01Z","timestamp":1554194341000},"page":"533-536","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of<i>trans<\/i>-diaqua(3,10-dimethyl-1,3,5,8,10,12-hexaazacyclotetradecane)copper(II) pamoate"],"prefix":"10.1107","volume":"75","author":[{"given":"Liudmyla V.","family":"Tsymbal","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Irina L.","family":"Andriichuk","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vladimir B.","family":"Arion","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3800-6697","authenticated-orcid":true,"given":"Yaroslaw D.","family":"Lampeka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,4,2]]},"reference":[{"key":"hb7810_bb1","doi-asserted-by":"crossref","first-page":"1102","DOI":"10.1021\/ic50030a003","volume":"4","author":"Bosnich","year":"1965","journal-title":"Inorg. 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