{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T08:50:16Z","timestamp":1736844616493,"version":"3.33.0"},"reference-count":28,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2019,4,2]],"date-time":"2019-04-02T00:00:00Z","timestamp":1554163200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,4,2]],"date-time":"2019-04-02T00:00:00Z","timestamp":1554163200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,3,28]]},"published-print":{"date-parts":[[2019,5,1]]},"abstract":"<jats:p>In the course of crystal-engineering experiments, crystals of the hydrated title salt, Na<jats:sub>10<\/jats:sub>[Pd<jats:sub>2<\/jats:sub>Cl<jats:sub>6<\/jats:sub>](C<jats:sub>4<\/jats:sub>H<jats:sub>9<\/jats:sub>SO<jats:sub>3<\/jats:sub>)<jats:sub>8<\/jats:sub>\u00b74H<jats:sub>2<\/jats:sub>O, were obtained from a water\/2-propanol solution of sodium <jats:italic>n<\/jats:italic>-butanesulfonate and sodium tetrachloridopalladate(II). In the crystal, sodium <jats:italic>n<\/jats:italic>-butanesulfonate anions and water molecules are arranged in an amphiphilic inverse bilayered cationic array represented by the formula {[Na<jats:sub>10<\/jats:sub>(C<jats:sub>4<\/jats:sub>H<jats:sub>9<\/jats:sub>SO<jats:sub>3<\/jats:sub>)<jats:sub>8<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>4<\/jats:sub>]<jats:sup>2+<\/jats:sup>}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>. Within this lamellar array: (i) a hydrophilic layer region parallel to the <jats:italic>bc<\/jats:italic> plane is established by the Na<jats:sup>+<\/jats:sup> cations, the H<jats:sub>2<\/jats:sub>O molecules (as aqua ligands in \u03ba<jats:italic>Na<\/jats:italic>,\u03ba<jats:italic>Na<\/jats:italic>\u2032-bridging coordination mode) and the O<jats:sub>3<\/jats:sub>S\u2013 groups of the sulfonate ions, and (ii) hydrophobic regions are present containing all the <jats:italic>n<\/jats:italic>-butyl groups in an almost parallel orientation, with the chain direction approximately perpendicular to the aforementioned hydrophilic layer. Unexpectedly, the flat centrosymmetric [Pd<jats:sub>2<\/jats:sub>Cl<jats:sub>6<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> anion in the structure is placed between the butyl groups, <jats:italic>within<\/jats:italic> the hydrophobic regions, but due to its appropriate length primarily bonded to the hydrophilic `inorganic' layer regions above and below the hydrophobic area <jats:italic>via<\/jats:italic> Pd\u2014Cl<jats:sub>t<\/jats:sub>...Na- and Pd\u2014Cl<jats:sub>t<\/jats:sub>...H\u2014O(H)\u2014Na-type (Cl<jats:sub>t<\/jats:sub> is terminal chloride) interactions. In addition to these hydrogen-bonding interactions, both aqua ligands are engaged in charge-supported S\u2014O...H\u2014O hydrogen bonds of a motif characterized by the <jats:italic>D<\/jats:italic>\n                  <jats:sub>4<\/jats:sub>\n                  <jats:sup>3<\/jats:sup>(9) graph-set descriptor within the hydrophilic region. The crystal structure of the title compound is the first reported for a metal <jats:italic>n<\/jats:italic>-butanesulfonate.<\/jats:p>","DOI":"10.1107\/s2056989019004201","type":"journal-article","created":{"date-parts":[[2019,4,2]],"date-time":"2019-04-02T08:39:01Z","timestamp":1554194341000},"page":"557-561","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal engineering with short-chained amphiphiles: decasodium octa-<i>n<\/i>-butanesulfonate di-\u03bc-chlorido-bis[dichloridopalladate(II)] tetrahydrate, a layered inorganic\u2013organic hybrid material"],"prefix":"10.1107","volume":"75","author":[{"given":"Felix","family":"Thoelen","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Walter","family":"Frank","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,4,2]]},"reference":[{"key":"wm5491_bb1","doi-asserted-by":"crossref","first-page":"3511","DOI":"10.1016\/S0277-5387(99)00289-2","volume":"18","author":"Bouquillon","year":"1999","journal-title":"Polyhedron"},{"key":"wm5491_bb2","unstructured":"Brandenburg, K. 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