{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T15:31:20Z","timestamp":1787067080401,"version":"build-2736575974"},"reference-count":35,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2019,4,9]],"date-time":"2019-04-09T00:00:00Z","timestamp":1554768000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,4,9]],"date-time":"2019-04-09T00:00:00Z","timestamp":1554768000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,4,5]]},"published-print":{"date-parts":[[2019,5,1]]},"abstract":"<jats:p>\n                    In the title compound, Na\n                    <jats:sup>+<\/jats:sup>\n                    [Me\n                    <jats:sub>3<\/jats:sub>\n                    NB\n                    <jats:sub>12<\/jats:sub>\n                    Cl\n                    <jats:sub>11<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    \u00b7SO\n                    <jats:sub>2<\/jats:sub>\n                    [systematic name: sodium 1-(trimethylammonio)undecachloro-\n                    <jats:italic>closo<\/jats:italic>\n                    -dodecaborate sulfur dioxide], the SO\n                    <jats:sub>2<\/jats:sub>\n                    molecule is\n                    <jats:italic>\u03b7<\/jats:italic>\n                    <jats:sup>1<\/jats:sup>\n                    -\n                    <jats:italic>O<\/jats:italic>\n                    -coordinated to the Na\n                    <jats:sup>+<\/jats:sup>\n                    cation. Surprisingly, the SO\n                    <jats:sub>2<\/jats:sub>\n                    molecule is more weakly bound to sodium than is found in other sodium\u2013SO\n                    <jats:sub>2<\/jats:sub>\n                    complexes and the SO\n                    <jats:sub>2<\/jats:sub>\n                    molecule is essentially undistorted compared to the structure of free SO\n                    <jats:sub>2<\/jats:sub>\n                    . The Na\n                    <jats:sup>+<\/jats:sup>\n                    cation has a coordination number of eight in a distorted twofold-capped trigonal prism and makes contacts to three individual boron cluster anions, resulting in an overall three-dimensional network. Although the number of known\n                    <jats:italic>\u03b7<\/jats:italic>\n                    <jats:sup>1<\/jats:sup>\n                    -\n                    <jats:italic>O<\/jats:italic>\n                    -coordinated SO\n                    <jats:sub>2<\/jats:sub>\n                    complexes is growing, sodium-SO\n                    <jats:sub>2<\/jats:sub>\n                    complexes are still rare.\n                  <\/jats:p>","DOI":"10.1107\/s2056989019004663","type":"journal-article","created":{"date-parts":[[2019,4,9]],"date-time":"2019-04-09T04:39:21Z","timestamp":1554784761000},"page":"607-610","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Na\n                    <sup>+<\/sup>\n                    [Me\n                    <sub>3<\/sub>\n                    NB\n                    <sub>12<\/sub>\n                    Cl\n                    <sub>11<\/sub>\n                    ]\n                    <sup>\u2212<\/sup>\n                    \u00b7SO\n                    <sub>2<\/sub>\n                    : a rare example of a sodium\u2013SO\n                    <sub>2<\/sub>\n                    complex"],"prefix":"10.1107","volume":"75","author":[{"given":"Carsten","family":"Jenne","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8033-7620","authenticated-orcid":true,"given":"Valentin","family":"van Lessen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2019,4,9]]},"reference":[{"key":"cq2030_bb1","doi-asserted-by":"crossref","first-page":"321","DOI":"10.1007\/s10870-005-9067-z","volume":"36","author":"Akku\u015f","year":"2006","journal-title":"J. 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