{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,22]],"date-time":"2026-01-22T08:23:25Z","timestamp":1769070205895,"version":"3.49.0"},"reference-count":49,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2019,4,25]],"date-time":"2019-04-25T00:00:00Z","timestamp":1556150400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,4,25]],"date-time":"2019-04-25T00:00:00Z","timestamp":1556150400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Open Access Publishing Fund of Clausthal University of Technology"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,4,15]]},"published-print":{"date-parts":[[2019,5,1]]},"abstract":"<jats:p>The centrosymmetric binuclear complex cation of the title compound, [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>6<\/jats:sub>)(C<jats:sub>12<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>](NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b7C<jats:sub>12<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>6<\/jats:sub>\u00b78H<jats:sub>2<\/jats:sub>O, is composed of a Cu<jats:sup>II<\/jats:sup> atom with a distorted trigonal\u2013bipyramidal coordination environment defined by four N atoms from two bidentate 1,10-phenanthroline ligands and one oxygen atom from one-half of the monodentate <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-(1,4-phenylenedicarbonyl)diglycinate anion. The asymmetric unit is completed by one-half of the <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-(1,4-phenylenedicarbonyl)diglycine solvent molecule, which is located on a centre of inversion, by one nitrate counter-anion and four water molecules. In the crystal, the cationic complexes are linked <jats:italic>via<\/jats:italic> intermolecular \u03c0\u2013\u03c0 stacking and through lone-pair...\u03c0 interactions involving the <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-(1,4-phenylenedicarbonyl)diglycinate anion and the phenanthroline ligands. The <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-(1,4-phenylenedicarbonyl)diglycine solvent molecule is involved in classical and non-classical hydrogen-bonding interactions, as well as \u03c0\u2013\u03c0 stacking interactions. The centroid-to-centroid distances between aromatic entities are in the range 3.5402\u2005(5)\u20134.3673\u2005(4)\u2005\u00c5. The crystal structure is stabilized by further C\u2014H...O contacts as well as by O\u2014H...O and N\u2014H...O hydrogen bonds between water molecules, the nitrate anions, the <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-(1,4-phenylenedicarbonyl)diglycinate ligands, <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032-(1,4-phenylenedicarbonyl)diglycine solvent molecules and phenanthroline ligands, giving rise to a supramolecular framework. A Hirshfeld surface analysis was carried out to quantify these interactions.<\/jats:p>","DOI":"10.1107\/s2056989019005164","type":"journal-article","created":{"date-parts":[[2019,4,25]],"date-time":"2019-04-25T09:58:50Z","timestamp":1556186330000},"page":"667-674","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":9,"title":["Crystal structure and Hirshfeld surface analysis of (\u03bc-2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetato-\u03ba<sup>2<\/sup>\n                  <i>O<\/i>:<i>O<\/i>\u2032)bis[bis(1,10-phenanthroline-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>,<i>N<\/i>\u2032)copper(II)] dinitrate <i>N<\/i>,<i>N<\/i>\u2032-(1,4-phenylenedicarbonyl)diglycine monosolvate octahydrate"],"prefix":"10.1107","volume":"75","author":[{"given":"Niels-Patrick","family":"Pook","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Arnold","family":"Adam","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mimoza","family":"Gjikaj","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,4,25]]},"reference":[{"key":"wm5501_bb1","doi-asserted-by":"crossref","first-page":"7149","DOI":"10.1016\/j.tet.2010.06.079","volume":"66","author":"Albrecht","year":"2010","journal-title":"Tetrahedron"},{"key":"wm5501_bb2","doi-asserted-by":"crossref","first-page":"1330","DOI":"10.1039\/b802352m","volume":"38","author":"Allendorf","year":"2009","journal-title":"Chem. 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