{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T08:55:45Z","timestamp":1790844945866,"version":"4.1.0"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2019,7,23]],"date-time":"2019-07-23T00:00:00Z","timestamp":1563840000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,7,23]],"date-time":"2019-07-23T00:00:00Z","timestamp":1563840000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Center of Science and Technology, Uzbekistan","award":["BA-FA\u2013 F7\u2013004"],"award-info":[{"award-number":["BA-FA\u2013 F7\u2013004"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,7,18]]},"published-print":{"date-parts":[[2019,8,1]]},"abstract":"<jats:p>The reaction of 2-methylthio-5-amino-1,3,4-thiadiazole (Me-SNTD; C<jats:sub>3<\/jats:sub>H<jats:sub>5<\/jats:sub>N<jats:sub>3<\/jats:sub>S<jats:sub>2<\/jats:sub>) with copper(II) acetate monohydrate [Cu(OAc)<jats:sub>2<\/jats:sub>\u00b7H<jats:sub>2<\/jats:sub>O; C<jats:sub>4<\/jats:sub>H<jats:sub>8<\/jats:sub>CuO<jats:sub>5<\/jats:sub>] resulted in the formation of the title binuclear compound, [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>2<\/jats:sub>H<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>5<\/jats:sub>N<jats:sub>3<\/jats:sub>S<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>] or [Cu<jats:sub>2<\/jats:sub>(OAc)<jats:sub>4<\/jats:sub>(Me-SNTD)<jats:sub>2<\/jats:sub>]. The structure has triclinic (<jats:italic>P<\/jats:italic> \\overline{1}) symmetry with a crystallographic inversion centre located at the midpoint of the line connecting the Cu atoms in the dimer. These two Cu atoms of the dimer [Cu...Cu = 2.6727\u2005(6)\u2005\u00c5] are held together by four carboxylate groups. Each Cu atom is further coordinated to the N atom of an Me-SNTD molecule and exhibits a Jahn\u2013Teller-distorted octahedral geometry. The dimers are connected into infinite chains by hydrogen bonds between the NH (Me-SNTD) and the carboxylate groups of neighbouring molecules, generating an <jats:italic>R<\/jats:italic>\n                  <jats:sup>2<\/jats:sup>\n                  <jats:sub>2<\/jats:sub>(12) ring motif. The molecules are further linked by C\u2014H...\u03c0 interactions between the thiadiazole rings and the methyl groups of the acetate units.<\/jats:p>","DOI":"10.1107\/s2056989019010272","type":"journal-article","created":{"date-parts":[[2019,7,23]],"date-time":"2019-07-23T08:43:18Z","timestamp":1563871398000},"page":"1239-1242","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":6,"title":["Crystal structure of tetra-\u03bc-acetato-bis[(5-amino-2-methylsulfanyl-1,3,4-thiadiazole-\u03ba<i>N<\/i>\n                  <sup>1<\/sup>)copper(II)]"],"prefix":"10.1107","volume":"75","author":[{"given":"Batirbay","family":"Torambetov","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaxnoza","family":"Kadirova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Turdibek","family":"Toshmurodov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jamshid Mengnorovich","family":"Ashurov","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nusrat Agzamovich","family":"Parpiev","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abdukhakim","family":"Ziyaev","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2019,7,23]]},"reference":[{"key":"cq2032_bb1","doi-asserted-by":"crossref","first-page":"601","DOI":"10.1007\/s00706-008-0099-x","volume":"140","author":"Abdel-Wahab","year":"2009","journal-title":"Monatsh. 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