{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:48:59Z","timestamp":1740174539134,"version":"3.37.3"},"reference-count":43,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2019,9,27]],"date-time":"2019-09-27T00:00:00Z","timestamp":1569542400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,9,27]],"date-time":"2019-09-27T00:00:00Z","timestamp":1569542400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Deutsche Forschungsgesellschaft"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,9,6]]},"published-print":{"date-parts":[[2019,10,1]]},"abstract":"<jats:p>The title compound, [Ni(C<jats:sub>64<\/jats:sub>H<jats:sub>33<\/jats:sub>F<jats:sub>10<\/jats:sub>N<jats:sub>5<\/jats:sub>S<jats:sub>2<\/jats:sub>)]\u00b7<jats:italic>x<\/jats:italic>CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, consists of discrete Ni<jats:sup>II<\/jats:sup> porphyrin complexes, in which the five-coordinate Ni<jats:sup>II<\/jats:sup> cations are in a distorted square-pyramidal coordination geometry. The four porphyrin nitrogen atoms are located in the basal plane of the pyramid, whereas the pyridine N atom is in the apical position. The porphyrin plane is strongly distorted and the Ni<jats:sup>II<\/jats:sup> cation is located above this plane by 0.241\u2005(3)\u2005\u00c5 and shifted in the direction of the coordinating pyridine nitrogen atom. The pyridine ring is not perpendicular to the N<jats:sub>4<\/jats:sub> plane of the porphyrin moiety, as observed for related compounds. In the crystal, the complexes are linked <jats:italic>via<\/jats:italic> weak C\u2014H...F hydrogen bonds into zigzag chains propagating in the [001] direction. Within this arrangement cavities are formed, in which highly disordered dichloromethane solvate molecules are located. No reasonable structural model could be found to describe this disorder and therefore the contribution of the solvent to the electron density was removed using the SQUEEZE option in <jats:italic>PLATON<\/jats:italic> [Spek (2015). <jats:italic>Acta Cryst<\/jats:italic>. C<jats:bold>71<\/jats:bold>, 9\u201318].<\/jats:p>","DOI":"10.1107\/s2056989019012453","type":"journal-article","created":{"date-parts":[[2019,9,27]],"date-time":"2019-09-27T08:30:25Z","timestamp":1569573025000},"page":"1558-1563","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of (15,20-bis(2,3,4,5,6-pentafluorophenyl)-5,10-{(4-methylpyridine-3,5-diyl)bis[(sulfanediylmethylene)[1,1\u2032-biphenyl]-4\u2032,2-diyl]}porphyrinato)nickel(II) dichloromethane <i>x<\/i>-solvate (<i>x<\/i> &gt; 1\/2)"],"prefix":"10.1107","volume":"75","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4436-8152","authenticated-orcid":true,"given":"Florian","family":"Gutzeit","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tjorge","family":"Neumann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christian","family":"N\u00e4ther","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rainer","family":"Herges","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,9,27]]},"reference":[{"key":"hb7846_bb1","doi-asserted-by":"crossref","first-page":"m42","DOI":"10.1107\/S205698901500153X","volume":"71","author":"Awasabisah","year":"2015","journal-title":"Acta Cryst. 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