{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T23:02:23Z","timestamp":1789081343158,"version":"build-2803163510"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2019,9,27]],"date-time":"2019-09-27T00:00:00Z","timestamp":1569542400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,9,27]],"date-time":"2019-09-27T00:00:00Z","timestamp":1569542400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Welch Foundation Departmental Research Grant Program","award":["U-0047"],"award-info":[{"award-number":["U-0047"]}]},{"name":"St. Mary's University Internal Faculty Research Grant Award"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,9,19]]},"published-print":{"date-parts":[[2019,10,1]]},"abstract":"<jats:p>The title phosphonate-based organic\u2013inorganic hybrid framework, poly[bis(dimethylammonium) [(\u03bc<jats:sub>4<\/jats:sub>-2,5-dihydroxybenzene-1,4-diphosphonato)zinc(II)]], {(C<jats:sub>2<\/jats:sub>H<jats:sub>8<\/jats:sub>N)<jats:sub>2<\/jats:sub>[Zn(C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>O<jats:sub>8<\/jats:sub>P<jats:sub>2<\/jats:sub>)]}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, was formed unexpectedly when dimethylammonium cations were formed from the <jats:italic>in situ<\/jats:italic> decarbonylation of the <jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dimethylformamide solvent. The framework is built up from ZnO<jats:sub>4<\/jats:sub> tetrahedra and bridging diphosphonate tetra-anions to generate a three-dimensional network comprising [100] channels occupied by the (CH<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>NH<jats:sub>2<\/jats:sub>\n                  <jats:sup>+<\/jats:sup> cations. Within the channels, an array of N\u2014H...O hydrogen bonds help to establish the structure. In addition, intramolecular O\u2014H...O hydrogen bonds between the appended \u2013OH groups of the phenyl ring and adjacent PO<jats:sub>3<\/jats:sub>\n                  <jats:sup>2\u2212<\/jats:sup> groups are observed.<\/jats:p>","DOI":"10.1107\/s2056989019012969","type":"journal-article","created":{"date-parts":[[2019,9,27]],"date-time":"2019-09-27T08:30:25Z","timestamp":1569573025000},"page":"1540-1543","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["<i>In situ<\/i> decarbonylation of <i>N<\/i>,<i>N<\/i>-dimethylformamide to form dimethylammonium cations in the hybrid framework compound {[(CH<sub>3<\/sub>)<sub>2<\/sub>NH<sub>2<\/sub>]<sub>2<\/sub>[Zn{O<sub>3<\/sub>PC<sub>6<\/sub>H<sub>2<\/sub>(OH)<sub>2<\/sub>PO<sub>3<\/sub>}]}<sub>\n                     <i>n<\/i>\n                  <\/sub>"],"prefix":"10.1107","volume":"75","author":[{"given":"Josemaria S.","family":"Soriano","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bryan E.","family":"Galeas","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paul","family":"Garrett","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ryan A.","family":"Flores","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juan L.","family":"Pinedo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tsuyoshi A.","family":"Kohlgruber","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel","family":"Felton","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pius O.","family":"Adelani","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2019,9,27]]},"reference":[{"key":"hb7847_bb1","doi-asserted-by":"crossref","first-page":"8909","DOI":"10.1002\/anie.201004797","volume":"49","author":"Adelani","year":"2010","journal-title":"Angew. Chem. Int. Ed."},{"key":"hb7847_bb2","doi-asserted-by":"crossref","first-page":"688","DOI":"10.1021\/ac9606315","volume":"69","author":"Brousseau","year":"1997","journal-title":"Anal. Chem."},{"key":"hb7847_bb3","unstructured":"Bruker (2015). APEX3 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"hb7847_bb4","doi-asserted-by":"crossref","first-page":"o1133","DOI":"10.1107\/S1600536807004783","volume":"63","author":"Chen","year":"2007","journal-title":"Acta Cryst. E"},{"key":"hb7847_bb5","doi-asserted-by":"crossref","first-page":"268","DOI":"10.1016\/S1359-0286(96)80094-5","volume":"1","author":"Clearfield","year":"1996","journal-title":"Curr. Opin. Solid State Mater. Sci."},{"key":"hb7847_bb6","first-page":"371","volume":"47","author":"Clearfield","year":"1998","journal-title":"Prog. Inorg. Chem."},{"key":"hb7847_bb7","doi-asserted-by":"crossref","first-page":"495","DOI":"10.1016\/S1359-0286(02)00151-1","volume":"6","author":"Clearfield","year":"2002","journal-title":"Curr. Opin. Solid State Mater. Sci."},{"key":"hb7847_bb8","doi-asserted-by":"crossref","first-page":"2185","DOI":"10.1021\/ic502639v","volume":"54","author":"Deria","year":"2015","journal-title":"Inorg. Chem."},{"key":"hb7847_bb9","doi-asserted-by":"crossref","first-page":"1034","DOI":"10.1021\/cr2002257","volume":"112","author":"Gagnon","year":"2012","journal-title":"Chem. Rev."},{"key":"hb7847_bb10","doi-asserted-by":"crossref","first-page":"1521","DOI":"10.1107\/S2056989016014948","volume":"72","author":"Hulushe","year":"2016","journal-title":"Acta Cryst. E"},{"key":"hb7847_bb11","doi-asserted-by":"crossref","first-page":"o2491","DOI":"10.1107\/S1600536804028685","volume":"60","author":"Karpova","year":"2004","journal-title":"Acta Cryst. E"},{"key":"hb7847_bb12","doi-asserted-by":"crossref","first-page":"5556","DOI":"10.1039\/b807938b","author":"Kirumakki","year":"2008","journal-title":"Chem. Commun."},{"key":"hb7847_bb13","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"hb7847_bb14","doi-asserted-by":"crossref","first-page":"10449","DOI":"10.1021\/ic701628f","volume":"46","author":"Liang","year":"2007","journal-title":"Inorg. Chem."},{"key":"hb7847_bb15","doi-asserted-by":"crossref","first-page":"1493","DOI":"10.1016\/j.ccr.2007.02.008","volume":"251","author":"Mao","year":"2007","journal-title":"Coord. Chem. Rev."},{"key":"hb7847_bb16","doi-asserted-by":"crossref","first-page":"7640","DOI":"10.1021\/jacs.5b04399","volume":"137","author":"Ramaswamy","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"hb7847_bb17","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"hb7847_bb18","unstructured":"Sheldrick, G. M. (2008b). CIFTAB. University of G\u00f6ttingen, Germany."},{"key":"hb7847_bb19","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"hb7847_bb20","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"hb7847_bb21","doi-asserted-by":"crossref","first-page":"o1778","DOI":"10.1107\/S160053681202096X","volume":"68","author":"Siddiqui","year":"2012","journal-title":"Acta Cryst. E"},{"key":"hb7847_bb22","doi-asserted-by":"crossref","first-page":"99","DOI":"10.1039\/C0SC00371A","volume":"2","author":"Zheng","year":"2011","journal-title":"Chem. Sci."},{"key":"hb7847_bb23","unstructured":"Zubieta, J., Zon, J., Brunet, E., Winpenny, R., Wright, P. A., Stock, N., Mao, J. G., Zheng, L.-M., Albrecht-Schmitt, T., Bujoli, B., Cahill, C., Murugavel, R., Rocha, J., Hix, G., Shimizu, G., Clearfield, A. & Demadis, K. (2011). Metal Phosphonate Chemistry: From Synthesis to Applications, 1st ed., edited by A. Clearfield & K. Demadis. UK: Royal Society of Chemistry."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2019\/10\/00\/hb7847\/hb7847.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2019\/10\/00\/hb7847\/hb7847.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:51:24Z","timestamp":1736765484000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989019012969"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,9,27]]},"references-count":23,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2019,10]]}},"alternative-id":["S2056989019012969"],"URL":"https:\/\/doi.org\/10.1107\/s2056989019012969","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989019012969\/hb7847sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989019012969\/hb7847Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,9,27]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?hb7847","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"5 August 2019","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"19 September 2019","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"27 September 2019","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?hb7847"}},{"value":"\u00a9 2019 Soriano et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}