{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,6,6]],"date-time":"2025-06-06T08:10:18Z","timestamp":1749197418815,"version":"3.37.3"},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2019,10,22]],"date-time":"2019-10-22T00:00:00Z","timestamp":1571702400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,10,22]],"date-time":"2019-10-22T00:00:00Z","timestamp":1571702400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,10,9]]},"published-print":{"date-parts":[[2019,11,1]]},"abstract":"<jats:p>The asymmetric unit of the title compound,<jats:italic>catena<\/jats:italic>-poly[[[(perchlorato-\u03ba<jats:italic>O<\/jats:italic>)copper(II)]-\u03bc-3-(3-carboxypropyl)-1,5,8,12-tetraaza-3-azoniacyclotetradecane-\u03ba<jats:sup>4<\/jats:sup><jats:italic>N<\/jats:italic><jats:sup>1<\/jats:sup>,<jats:italic>N<\/jats:italic><jats:sup>5<\/jats:sup>,<jats:italic>N<\/jats:italic><jats:sup>8<\/jats:sup>,<jats:italic>N<\/jats:italic><jats:sup>12<\/jats:sup>] bis(perchlorate)], {[Cu(C<jats:sub>13<\/jats:sub>H<jats:sub>30<\/jats:sub>N<jats:sub>5<\/jats:sub>O<jats:sub>2<\/jats:sub>)(ClO<jats:sub>4<\/jats:sub>)](ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, (I), consists of a macrocyclic cation, one coordinated perchlorate anion and two perchlorate ions as counter-anions. The metal ion is coordinated in a tetragonally distorted octahedral geometry by the four secondary N atoms of the macrocyclic ligand, the mutually<jats:italic>trans<\/jats:italic>O atoms of the perchlorate anion and the carbonyl O atom of the protonated carboxylic acid group of a neighbouring cation. The average equatorial Cu\u2014N bond lengths [2.01\u2005(6)\u2005\u00c5] are significantly shorter than the axial Cu\u2014O bond lengths [2.379\u2005(8)\u2005\u00c5 for carboxylate and average 2.62\u2005(7)\u2005\u00c5 for disordered perchlorate]. The coordinated macrocyclic ligand in (I) adopts the most energetically favourable<jats:italic>trans<\/jats:italic>-III conformation with an equatorial orientation of the substituent at the protonated distal 3-position N atom in a six-membered chelate ring. The coordination of the carboxylic acid group of the cation to a neighbouring complex unit results in the formation of infinite chains running along the<jats:italic>b<\/jats:italic>-axis direction, which are crosslinked by N\u2014H...O hydrogen bonds between the secondary amine groups of the macrocycle and O atoms of the perchlorate counter-anions to form sheets lying parallel to the (001) plane. Additionally, the extended structure of (I) is consolidated by numerous intra- and interchain C\u2014H...O contacts.<\/jats:p>","DOI":"10.1107\/s205698901901377x","type":"journal-article","created":{"date-parts":[[2019,10,22]],"date-time":"2019-10-22T14:48:47Z","timestamp":1571755727000},"page":"1700-1704","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["The first structural characterization of the protonated azacyclam ligand in<i>catena<\/i>-poly[[[(perchlorato)copper(II)]-\u03bc-3-(3-carboxypropyl)-1,5,8,12-tetraaza-3-azoniacyclotetradecane] bis(perchlorate)]"],"prefix":"10.1107","volume":"75","author":[{"given":"Liudmyla V.","family":"Tsymbal","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vladimir B.","family":"Arion","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3800-6697","authenticated-orcid":true,"given":"Yaroslaw D.","family":"Lampeka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,10,22]]},"reference":[{"key":"hb7857_bb1","doi-asserted-by":"crossref","first-page":"1015","DOI":"10.1107\/S2056989019008387","volume":"75","author":"Andriichuk","year":"2019","journal-title":"Acta Cryst. 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