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The mean planes of the two pyridine ligands are rotated with respect to each other by 90\u00b0. Charge balance is achieved by one protonated pyridine molecule that is hydrogen bonded to one additional pyridine solvent molecule, with both located on crystallographic mirror planes and again rotated by exactly 90\u00b0. The pyridinium H atom was refined as disordered between both pyridine N atoms in a 70:30 ratio, leading to a linear N\u2014H...N hydrogen bond. In the crystal, discrete complexes are linked by weak C\u2014H...S hydrogen bonds into chains that are connected by additional C\u2014H...S hydrogen bonding <jats:italic>via<\/jats:italic> the pyridinium cations and solvent molecules into layers and finally into a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s2056989019014488","type":"journal-article","created":{"date-parts":[[2019,11,15]],"date-time":"2019-11-15T08:20:35Z","timestamp":1573806035000},"page":"1875-1879","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of pyridinium tetraisothiocyanatodipyridinechromium(III) pyridine monosolvate"],"prefix":"10.1107","volume":"75","author":[{"given":"Tristan","family":"Neumann","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Inke","family":"Jess","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christian","family":"N\u00e4ther","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,11,15]]},"reference":[{"key":"lh5933_bb1","doi-asserted-by":"crossref","first-page":"290","DOI":"10.1016\/j.jpcs.2018.11.001","volume":"130","author":"Baran","year":"2019","journal-title":"J. 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