{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:01Z","timestamp":1740174541322,"version":"3.37.3"},"reference-count":17,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2019,11,5]],"date-time":"2019-11-05T00:00:00Z","timestamp":1572912000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2019,11,5]],"date-time":"2019-11-05T00:00:00Z","timestamp":1572912000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003579","name":"University of Toronto","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003579","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,10,28]]},"published-print":{"date-parts":[[2019,12,1]]},"abstract":"<jats:p>The title compound, [IrZnI<jats:sub>2<\/jats:sub>(C<jats:sub>10<\/jats:sub>H<jats:sub>15<\/jats:sub>)(C<jats:sub>3<\/jats:sub>H<jats:sub>9<\/jats:sub>P)<jats:sub>2<\/jats:sub>]\u00b70.5C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub> or [Cp*(PMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>Ir]-[ZnI<jats:sub>2<\/jats:sub>] (Cp* = <jats:italic>cyclo<\/jats:italic>-C<jats:sub>5<\/jats:sub>Me<jats:sub>5<\/jats:sub>) was obtained and characterized as its benzene solvate [Cp*(PMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>Ir]-[ZnI<jats:sub>2<\/jats:sub>]\u00b70.5C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>. The bimetallic complex in this structure contains the Lewis-acidic fragment ZnI<jats:sub>2<\/jats:sub> bonded to the Lewis-basic fragment Cp*(PMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>Ir, with an Ir\u2014Zn bond distance of 2.452\u2005(1)\u2005\u00c5. The compound was obtained by reacting [Cp*(PMe<jats:sub>3<\/jats:sub>)IrI<jats:sub>2<\/jats:sub>] with 2-Ad<jats:sub>2<\/jats:sub>Zn (2-Ad = 2-adamantyl), resulting in the reduction of the Ir<jats:sup>III<\/jats:sup> complex and formation of the Ir<jats:sup>I<\/jats:sup>\u2013Zn<jats:sup>II<\/jats:sup> adduct. The crystal studied was a twin by non-merohedry with a refined BASF parameter of 0.223\u2005(1).<\/jats:p>","DOI":"10.1107\/s2056989019014622","type":"journal-article","created":{"date-parts":[[2019,11,5]],"date-time":"2019-11-05T09:59:54Z","timestamp":1572947994000},"page":"1824-1827","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["An iridium complex with an unsupported Ir\u2014Zn bond: diiodido(\u03b7<sup>5<\/sup>-pentamethylcyclopentadienyl)bis(trimethylphosphane)iridiumzinc(<i>Ir<\/i>\u2014<i>Zn<\/i>) benzene hemisolvate"],"prefix":"10.1107","volume":"75","author":[{"given":"Fioralba","family":"Taullaj","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alan J.","family":"Lough","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7345-1716","authenticated-orcid":true,"given":"Ulrich","family":"Fekl","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,11,5]]},"reference":[{"key":"zl2763_bb1","doi-asserted-by":"crossref","first-page":"6212","DOI":"10.1039\/C7DT00428A","volume":"46","author":"Armstrong","year":"2017","journal-title":"Dalton Trans."},{"key":"zl2763_bb2","unstructured":"Bruker (2012). 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