{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T04:34:17Z","timestamp":1773808457066,"version":"3.50.1"},"reference-count":28,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2020,1,1]],"date-time":"2020-01-01T00:00:00Z","timestamp":1577836800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2020,1,1]],"date-time":"2020-01-01T00:00:00Z","timestamp":1577836800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,12,3]]},"published-print":{"date-parts":[[2020,1,1]]},"abstract":"<jats:p>The polymeric title compound, [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>2<\/jats:sub>H<jats:sub>3<\/jats:sub>N)<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>6<\/jats:sub>S<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>](PF<jats:sub>6<\/jats:sub>)<jats:sub>2<\/jats:sub>, represents an example of a one-dimensional coordination polymer resulting from the reaction of [Cu(MeCN)<jats:sub>4<\/jats:sub>][PF<jats:sub>6<\/jats:sub>] with 1,3-dithiolane. The cationic one-dimensional ribbon consists of two copper(I) centers each ligated by one acetonitrile molecule and interconnected through two bridging 1,3-dithiolane ligands. One S-donor site of each ligand is \u03ba<jats:sup>1<\/jats:sup>-bound to Cu, whereas the second S atom acts as a four-electron donor, bridging two Cu atoms in a \u03ba<jats:sup>4<\/jats:sup>-bonding mode. The positive charge of each copper cation is compensated for by a hexafluoridophosphate counter-ion. 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