{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:02Z","timestamp":1740174542355,"version":"3.37.3"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2020,1,1]],"date-time":"2020-01-01T00:00:00Z","timestamp":1577836800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2020,1,1]],"date-time":"2020-01-01T00:00:00Z","timestamp":1577836800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["51602130"],"award-info":[{"award-number":["51602130"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2019,12,15]]},"published-print":{"date-parts":[[2020,1,1]]},"abstract":"<jats:p>The solvated title salt, [Ir(C<jats:sub>9<\/jats:sub>H<jats:sub>7<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>8<\/jats:sub>H<jats:sub>6<\/jats:sub>N<jats:sub>2<\/jats:sub>)]PF<jats:sub>6<\/jats:sub>\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, was obtained from the reaction between 1,8-naphthyridine (NAP) and an orthometalated iridium(III) precursor containing a 1-phenylpyrazole (ppz) ligand. The asymmetric unit comprises one [Ir(ppz)<jats:sub>2<\/jats:sub>(NAP)]<jats:sup>+<\/jats:sup> cation, one PF<jats:sub>6<\/jats:sub>\n                  <jats:sup>\u2212<\/jats:sup> counter-ion and one CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> solvent molecule. The central Ir<jats:sup>III<\/jats:sup> atom of the [Ir(ppz)<jats:sub>2<\/jats:sub>(NAP)]<jats:sup>+<\/jats:sup> cation is distorted-octahedrally coordinated by four N atoms and two C atoms, whereby two N atoms stem from the NAP ligand while the ppz ligands ligate through one N and one C atom each. In the crystal, the [Ir(ppz)<jats:sub>2<\/jats:sub>(NAP)]<jats:sup>+<\/jats:sup> cations and PF<jats:sub>6<\/jats:sub>\n                  <jats:sup>\u2212<\/jats:sup> counter-ions are connected with each other through weak intermolecular C\u2014H...F hydrogen bonds. Together with an additional C\u2014H...F interaction involving the solvent molecule, a three-dimensional network structure is formed.<\/jats:p>","DOI":"10.1107\/s2056989019016773","type":"journal-article","created":{"date-parts":[[2019,12,20]],"date-time":"2019-12-20T08:28:16Z","timestamp":1576830496000},"page":"82-85","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystal structure of (1,8-naphthyridine-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>,<i>N<\/i>\u2032)[2-(1<i>H<\/i>-pyrazol-1-yl)phenyl-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>\n                  <sup>2<\/sup>,<i>C<\/i>\n                  <sup>1<\/sup>]iridium(III) hexafluoridophosphate dichloromethane monosolvate"],"prefix":"10.1107","volume":"76","author":[{"given":"Yunfeng","family":"Ye","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guodong","family":"Tang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jun","family":"Qian","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,1,1]]},"reference":[{"key":"wm5533_bb1","unstructured":"Bruker (2016). 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