{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T15:02:16Z","timestamp":1761490936942,"version":"3.37.3"},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2020,1,17]],"date-time":"2020-01-17T00:00:00Z","timestamp":1579219200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2020,1,17]],"date-time":"2020-01-17T00:00:00Z","timestamp":1579219200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100001602","name":"Science Foundation Ireland","doi-asserted-by":"crossref","award":["SFI, IvP 13\/IA\/1894"],"award-info":[{"award-number":["SFI, IvP 13\/IA\/1894"]}],"id":[{"id":"10.13039\/501100001602","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100007601","name":"Horizon 2020","doi-asserted-by":"publisher","award":["FET-OPEN grant agreement o. 828779"],"award-info":[{"award-number":["FET-OPEN grant agreement o. 828779"]}],"id":[{"id":"10.13039\/501100007601","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2020,1,14]]},"published-print":{"date-parts":[[2020,2,1]]},"abstract":"<jats:p>The crystal structures of the title compounds, two solvates (CHCl<jats:sub>3<\/jats:sub> and THF) of a symmetric and highly substituted porphyrin, C<jats:sub>44<\/jats:sub>H<jats:sub>2<\/jats:sub>Br<jats:sub>8<\/jats:sub>F<jats:sub>20<\/jats:sub>N<jats:sub>4<\/jats:sub> or OBrTPFPP, are described. These structures each feature a non-planar porphyrin ring, exhibiting a similar conformation of the strained ring independent of solvent identity. These distorted porphyrins are able to form hydrogen bonds and sub-van der Waals halogen interactions with enclathrated solvent; supramolecular interactions of proximal macrocycles are additionally affected by solvent choice. The crystal studied for compound <jats:bold>1\u00b7CHCl<jats:sub>3<\/jats:sub>\n                  <\/jats:bold> was refined as an inversion twin. One pentafluorophenyl group was modelled as disordered over two sites [occupancy ratio = 0.462\u2005(7):0.538\u2005(7)]. The chloroform solvate was also modelled as disordered over two orientations [occupancy ratio = 0.882\u2005(7): 0.118\u2005(7).<\/jats:p>","DOI":"10.1107\/s2056989020000432","type":"journal-article","created":{"date-parts":[[2020,1,17]],"date-time":"2020-01-17T09:25:03Z","timestamp":1579253103000},"page":"214-220","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structures of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin as the chloroform monosolvate and tetrahydrofuran monosolvate"],"prefix":"10.1107","volume":"76","author":[{"given":"Christopher J.","family":"Kingsbury","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1656-3177","authenticated-orcid":true,"given":"Keith J.","family":"Flanagan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marc","family":"Kielmann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Brendan","family":"Twamley","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7467-1654","authenticated-orcid":true,"given":"Mathias O.","family":"Senge","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,1,17]]},"reference":[{"key":"tx2016_bb1","doi-asserted-by":"crossref","first-page":"4925","DOI":"10.1039\/C9CC01547G","volume":"55","author":"Aoki","year":"2019","journal-title":"Chem. 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