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The two N atoms and two O atoms around the metal center are <jats:italic>trans<\/jats:italic> to each other, with an O\u2014Cu\u2014O bond angle of 177.90\u2005(16)\u00b0 and a N\u2014Cu\u2014N bond angle of 177.8\u2005(2)\u00b0. The average distances between the Cu<jats:sup>II<\/jats:sup> atom and the coordinated O and N atoms are 1.892\u2005(4) and 1.976\u2005(4)\u2005\u00c5, respectively. In the crystal, complexes are linked by C\u2014H...O hydrogen bonds and by \u03c0\u2013\u03c0 interactions involving adjacent naphthalene ring systems [centroid\u2013centroid distance = 3.679\u2005(4)\u2005\u00c5]. The disordered DMSO molecules interact weakly with the complex molecules, being positioned in the voids left by the packing arrangement of the square-planar complexes. 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