{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:06Z","timestamp":1740174546422,"version":"3.37.3"},"reference-count":38,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2020,4,3]],"date-time":"2020-04-03T00:00:00Z","timestamp":1585872000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2020,4,3]],"date-time":"2020-04-03T00:00:00Z","timestamp":1585872000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"NSF","award":["CHE-1725028"],"award-info":[{"award-number":["CHE-1725028"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2020,3,30]]},"published-print":{"date-parts":[[2020,5,1]]},"abstract":"<jats:p>The sexadentate ligand 1,1,1-tris[(salicylideneamino)methyl]ethane has been reported numerous times in its triply deprotonated form coordinated to transition metals and lanthanides, yet it has been rarely employed with main-group elements, including in substituted forms. Its structures with gallium and indium are reported as solvates, namely, ({[(2,2-bis{[(2-oxidobenzylidene)amino-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>,<jats:italic>O<\/jats:italic>]methyl}propyl)imino]methyl}phenololato-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>,<jats:italic>O<\/jats:italic>)gallium(III) pyridine monosolvate, [Ga(C<jats:sub>26<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>3<\/jats:sub>O3)]\u00b7C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>N, the acetonitrile 0.75-solvate, [Ga(C<jats:sub>26<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>3<\/jats:sub>O<jats:sub>3<\/jats:sub>)]\u00b70.75C<jats:sub>2<\/jats:sub>H<jats:sub>3<\/jats:sub>N, and ({[(2,2-bis{[(2-oxidobenzylidene)amino-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>,<jats:italic>O<\/jats:italic>]methyl}propyl)imino]methyl}phenololato-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>,<jats:italic>O<\/jats:italic>)indium(III) dichloromethane monosolvate, [In(C<jats:sub>26<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>3<\/jats:sub>O<jats:sub>3<\/jats:sub>)]\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>. All three metal complexes are pseudo-octahedral and each structure contains multiple weak C\u2014H...O and\/or C\u2014H...N intermolecular hydrogen-bonding interactions. The syntheses and additional characterization in the forms of melting points, high-resolution mass spectra, infra-red (IR) spectra, and <jats:sup>1<\/jats:sup>H and <jats:sup>13<\/jats:sup>C NMR spectra are also reported.<\/jats:p>","DOI":"10.1107\/s2056989020004375","type":"journal-article","created":{"date-parts":[[2020,4,3]],"date-time":"2020-04-03T09:35:45Z","timestamp":1585906545000},"page":"615-620","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structures of {1,1,1-tris[(salicylaldimino)methyl]ethane}gallium as both a pyridine solvate and an acetonitrile 0.75-solvate and {1,1,1-tris[(salicylaldimino)methyl]ethane}indium dichloromethane solvate"],"prefix":"10.1107","volume":"76","author":[{"given":"Dominic L.","family":"Ventura","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5461-1825","authenticated-orcid":true,"given":"William W.","family":"Brennessel","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"William S.","family":"Durfee","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,4,3]]},"reference":[{"key":"ex2030_bb1","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1107\/S0021889898007717","volume":"32","author":"Altomare","year":"1999","journal-title":"J. Appl. Cryst."},{"key":"ex2030_bb2","doi-asserted-by":"crossref","first-page":"6238","DOI":"10.1039\/c1dt10126a","volume":"40","author":"Arrowsmith","year":"2011","journal-title":"Dalton Trans."},{"key":"ex2030_bb3","unstructured":"Bruker (2009). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"ex2030_bb4","unstructured":"Bruker (2011). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"ex2030_bb5","doi-asserted-by":"crossref","first-page":"1837","DOI":"10.1039\/a801046c","author":"Deeney","year":"1998","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"ex2030_bb6","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"ex2030_bb7","doi-asserted-by":"crossref","first-page":"1035","DOI":"10.1039\/c39950001035","author":"Drew","year":"1995","journal-title":"J. Chem. Soc. Chem. Commun."},{"key":"ex2030_bb8","unstructured":"Evans, D. F. & Jakubovic, D. A. (1988). J. Chem. Soc. Dalton Trans. pp. 2927."},{"key":"ex2030_bb9","doi-asserted-by":"crossref","first-page":"4298","DOI":"10.1002\/ejic.200900561","author":"Gottschaldt","year":"2009","journal-title":"Eur. J. Inorg. Chem."},{"key":"ex2030_bb10","first-page":"228","volume":"34","author":"Green","year":"1993","journal-title":"J. Nucl. Med."},{"key":"ex2030_bb11","doi-asserted-by":"crossref","first-page":"3689","DOI":"10.1021\/ja00324a058","volume":"106","author":"Green","year":"1984","journal-title":"J. Am. Chem. Soc."},{"key":"ex2030_bb12","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"ex2030_bb13","doi-asserted-by":"crossref","first-page":"12302","DOI":"10.1021\/acs.inorgchem.9b01802","volume":"58","author":"Gut","year":"2019","journal-title":"Inorg. Chem."},{"key":"ex2030_bb14","unstructured":"Johnston, T. E. (1974). (E. I. du Pont de Nemours & Co., Wilmington, Delaware, USA). Metal-Deactivated Organic Compositions and Process Therefor. US Patent 3,843,536, Oct. 22, 1974."},{"key":"ex2030_bb15","doi-asserted-by":"crossref","first-page":"1445","DOI":"10.1039\/c2nj40171a","volume":"36","author":"Katsuta","year":"2012","journal-title":"New J. Chem."},{"key":"ex2030_bb16","doi-asserted-by":"crossref","first-page":"1950","DOI":"10.1039\/B517503H","author":"Kobayashi","year":"2006","journal-title":"Chem. Commun."},{"key":"ex2030_bb17","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1080\/10587250008038241","volume":"342","author":"Kojima","year":"2000","journal-title":"Mol. Cryst. Liq. Cryst."},{"key":"ex2030_bb18","doi-asserted-by":"crossref","first-page":"482","DOI":"10.1246\/cl.2000.482","volume":"29","author":"Kojima","year":"2000","journal-title":"Chem. Lett."},{"key":"ex2030_bb19","doi-asserted-by":"crossref","first-page":"5400","DOI":"10.1021\/ic00052a015","volume":"31","author":"Liu","year":"1992","journal-title":"Inorg. Chem."},{"key":"ex2030_bb20","doi-asserted-by":"crossref","first-page":"1756","DOI":"10.1021\/ic00061a036","volume":"32","author":"Liu","year":"1993","journal-title":"Inorg. Chem."},{"key":"ex2030_bb21","doi-asserted-by":"crossref","first-page":"4268","DOI":"10.1021\/ic00072a019","volume":"32","author":"Liu","year":"1993","journal-title":"Inorg. Chem."},{"key":"ex2030_bb22","doi-asserted-by":"crossref","first-page":"567","DOI":"10.1016\/0969-8051(96)00040-6","volume":"23","author":"Marmion","year":"1996","journal-title":"Nucl. Med. Biol."},{"key":"ex2030_bb23","doi-asserted-by":"crossref","first-page":"277","DOI":"10.1016\/0047-0740(81)90034-6","volume":"8","author":"Moerlein","year":"1981","journal-title":"Int. J. Nucl. Med. Biol."},{"key":"ex2030_bb24","doi-asserted-by":"crossref","first-page":"842","DOI":"10.1246\/cl.2001.842","volume":"30","author":"Ohta","year":"2001","journal-title":"Chem. Lett."},{"key":"ex2030_bb25","unstructured":"Rigaku OD (2019). CrysAlis PRO. Rigaku Oxford Diffraction, Yarnton, England."},{"key":"ex2030_bb26","doi-asserted-by":"crossref","first-page":"181","DOI":"10.1016\/S0021-9673(99)00379-9","volume":"844","author":"Robards","year":"1999","journal-title":"J. Chromatogr. A"},{"key":"ex2030_bb27","doi-asserted-by":"crossref","first-page":"751","DOI":"10.1107\/S0567739476001551","volume":"32","author":"Shannon","year":"1976","journal-title":"Acta Cryst. A"},{"key":"ex2030_bb28","unstructured":"Sheldrick, G. M. (1996). SADABS. University of G\u00f6ttingen, Germany."},{"key":"ex2030_bb30","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"ex2030_bb31","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"ex2030_bb32","doi-asserted-by":"crossref","first-page":"716","DOI":"10.1246\/bcsj.81.716","volume":"81","author":"Sunatsuki","year":"2008","journal-title":"Bull. Chem. Soc. Jpn"},{"key":"ex2030_bb33","doi-asserted-by":"crossref","first-page":"448","DOI":"10.1107\/S0108767312014535","volume":"68","author":"Thorn","year":"2012","journal-title":"Acta Cryst. A"},{"key":"ex2030_bb34","unstructured":"Urushigawa, Y., Yuki, M., Ishikita, H., Inazu, T. & Yoshino, T. (1977). Memoirs of the Faculty Science, Kyishu University, Ser. C. 10, 125-131."},{"key":"ex2030_bb35","doi-asserted-by":"crossref","first-page":"598","DOI":"10.1246\/bcsj.81.598","volume":"81","author":"Yamaguchi","year":"2008","journal-title":"Bull. Chem. Soc. Jpn"},{"key":"ex2030_bb36","doi-asserted-by":"crossref","first-page":"5736","DOI":"10.1021\/ic8000575","volume":"47","author":"Yamaguchi","year":"2008","journal-title":"Inorg. Chem."},{"key":"ex2030_bb37","doi-asserted-by":"crossref","first-page":"1048","DOI":"10.1039\/B401033G","author":"Yamaguchi","year":"2004","journal-title":"Chem. Commun."},{"key":"ex2030_bb38","doi-asserted-by":"crossref","first-page":"37","DOI":"10.2116\/xraystruct.26.37","volume":"26","author":"Yokoyama","year":"2010","journal-title":"X-ray Struct. Anal. Online"},{"key":"ex2030_bb39","first-page":"327","volume":"19","author":"Zhang","year":"1992","journal-title":"Nucl. Med. Biol."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2020\/05\/00\/ex2030\/ex2030.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2020\/05\/00\/ex2030\/ex2030.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:07:16Z","timestamp":1736766436000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989020004375"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,4,3]]},"references-count":38,"journal-issue":{"issue":"5","published-online":{"date-parts":[[2020,5]]}},"alternative-id":["S2056989020004375"],"URL":"https:\/\/doi.org\/10.1107\/s2056989020004375","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989020004375\/ex2030sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989020004375\/ex20301asup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989020004375\/ex20301bsup3.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989020004375\/ex20302sup4.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2020,4,3]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?ex2030","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"22 February 2020","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"30 March 2020","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"3 April 2020","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?ex2030"}},{"value":"\u00a9 2020 Ventura et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}