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The cobalt core exhibits an approximately square-pyramidal geometry with partially reduced thienyl radical monoanionic ligands. The supramolecular network is consolidated by hydrogen-bonding interactions primarily with nitrogen, sulfur and chlorine atoms, as well as parallel displaced \u03c0-stacking of the aryl rings. The UV\u2013vis, IR, and CV data are also consistent with monoanionic dithiolene ligands and an overall Co<jats:sup>II<\/jats:sup> oxidation state.<\/jats:p>","DOI":"10.1107\/s2056989020005447","type":"journal-article","created":{"date-parts":[[2020,4,24]],"date-time":"2020-04-24T08:44:23Z","timestamp":1587717863000},"page":"736-741","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["A five-coordinate cobalt bis(dithiolene)\u2013phosphine complex [Co(pdt)<sub>2<\/sub>(PTA)] (pdt = phenyldithiolene; PTA = 1,3,5-triaza-7-phosphaadamantane)"],"prefix":"10.1107","volume":"76","author":[{"given":"DaShawn","family":"Williams","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jacob P.","family":"Brannon","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Perumalreddy","family":"Chandrasekaran","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3778-207X","authenticated-orcid":true,"given":"S. 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