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Each pentacopper(II) metallacrown contains four Cu<jats:sup>II<\/jats:sup> ions in the MC ring and a Cu<jats:sup>II<\/jats:sup> ion captured in the central cavity. Each Cu<jats:sup>II<\/jats:sup> ion is four-coordinate with a square-planar geometry. The anionic {Cu[12-MC<jats:sub>Cu(II)N(shi)<\/jats:sub>-4]}<jats:sup>2\u2212<\/jats:sup> is charged-balanced by the presence of a <jats:italic>cis<\/jats:italic>-[Mn(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>(DMF)<jats:sub>4<\/jats:sub>]<jats:sup>2+<\/jats:sup> cation located in the lattice. In addition, the octahedral Mn<jats:sup>II<\/jats:sup> counter-cation is hydrogen bonded to both MC anions <jats:italic>via<\/jats:italic> the coordinated water molecules of the Mn<jats:sup>II<\/jats:sup> ion. The water molecules form hydrogen bonds with the phenolate and carbonyl oxygen atoms of the shi<jats:sup>3\u2212<\/jats:sup> ligands of the MCs.<\/jats:p>","DOI":"10.1107\/s2056989020005770","type":"journal-article","created":{"date-parts":[[2020,4,30]],"date-time":"2020-04-30T10:32:21Z","timestamp":1588242741000},"page":"747-751","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis and crystal structure of a pentacopper(II) 12-metallacrown-4: <i>cis<\/i>-diaquatetrakis(dimethylformamide-\u03ba<i>O<\/i>)manganese(II) tetrakis(\u03bc<sub>3<\/sub>-<i>N<\/i>,2-dioxidobenzene-1-carboximidate)pentacopper(II) dimethylformamide monosolvate"],"prefix":"10.1107","volume":"76","author":[{"given":"Gerard P.","family":"Van Trieste III","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Matthias","family":"Zeller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4831-2911","authenticated-orcid":true,"given":"Curtis M.","family":"Zaleski","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,4,30]]},"reference":[{"key":"yk2128_bb1","doi-asserted-by":"crossref","first-page":"6482","DOI":"10.1002\/chem.201600562","volume":"22","author":"Atzeri","year":"2016","journal-title":"Chem. 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