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The structure <jats:bold>1<\/jats:bold> has monoclinic symmetry (<jats:italic>C<\/jats:italic>2\/<jats:italic>c<\/jats:italic>) and the asymmetric unit contains half of the compound. Title compound <jats:bold>2<\/jats:bold> has triclinic symmetry (<jats:italic>P<\/jats:italic>\\overline{1}) and the asymmetric unit is half of an inversion-symmetric aggregate. Both compounds consist of an alkali metal, an aminoalkoxide and a 2-propanol compound. Furthermore, the dimeric sodium aggregate <jats:bold>2<\/jats:bold> is build up by hydrogen bonding through the 2-propanol and the alkoxides. Compound <jats:bold>1<\/jats:bold> does not exhibit hydrogen bonding, due to the fact that the 2-propanol is deprotonated. In compound <jats:bold>1<\/jats:bold>, benzene appeared as co-crystallate, but was suppressed by solvent masking because of strong disorder. The formula mass and density do not take account of the solvent.<\/jats:p>","DOI":"10.1107\/s2056989020006659","type":"journal-article","created":{"date-parts":[[2020,5,29]],"date-time":"2020-05-29T12:29:46Z","timestamp":1590755386000},"page":"948-953","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structures of [Li<sub>7<\/sub>(<i>i<\/i>-PrO)<sub>3<\/sub>(C<sub>4<\/sub>H<sub>10<\/sub>NO)<sub>3<\/sub>]<sub>2<\/sub>O and [Na(<i>i<\/i>-PrOH)<sub>2<\/sub>(C<sub>8<\/sub>H<sub>18<\/sub>NO<sub>2<\/sub>)]<sub>2<\/sub>"],"prefix":"10.1107","volume":"76","author":[{"given":"Rebecca","family":"Scheel","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kathrin","family":"Louven","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Carsten","family":"Strohmann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,5,29]]},"reference":[{"key":"vm2233_bb1","doi-asserted-by":"crossref","first-page":"1651","DOI":"10.1039\/b110708a","author":"Andrews","year":"2002","journal-title":"J. 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