{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,16]],"date-time":"2026-02-16T02:48:42Z","timestamp":1771210122398,"version":"3.50.1"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2020,6,19]],"date-time":"2020-06-19T00:00:00Z","timestamp":1592524800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2020,6,19]],"date-time":"2020-06-19T00:00:00Z","timestamp":1592524800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Center of Science and Technology, Uzbekistan","award":["BA\u2013FA\u2013F7\u2013004"],"award-info":[{"award-number":["BA\u2013FA\u2013F7\u2013004"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2020,6,11]]},"published-print":{"date-parts":[[2020,7,1]]},"abstract":"<jats:p>During systematic investigations of the biological action enhancement of well known compounds, a new metal complex, namely, bis(3,5-dinitrobenzoato)(ethane-1,2-diamine)zinc(II), [Zn(C<jats:sub>7<\/jats:sub>H<jats:sub>3<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>6<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>2<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)], was synthesized and the structure of its orthorhombic form has determined. The synthesis and crystal structure of the monoclinic polymorph has previously been reported [Ibragimov <jats:italic>et al.<\/jats:italic> (2020). <jats:italic>Rep. Uzb. Acad. Sci.<\/jats:italic> \n                  <jats:bold>1<\/jats:bold>, 45\u201350]. The zinc ion has a distorted tetrahedral environment formed by two monodentate 3,5-dinitrobenzoato anions and chelating ethylenediamine molecule. In the crystal, the complex molecules are linked by N\u2014H...O and C\u2014H...O hydrogen bonds into a two-dimensional network parallel to the <jats:italic>ac<\/jats:italic> plane. The Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H...O\/O...H (43.4%) and O...C\/C...O (17.7%) interactions.<\/jats:p>","DOI":"10.1107\/s2056989020007938","type":"journal-article","created":{"date-parts":[[2020,6,19]],"date-time":"2020-06-19T08:28:27Z","timestamp":1592555307000},"page":"1113-1116","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structure and Hirshfeld surface analysis of the orthorhombic polymorph of a Zn<sup>II<\/sup> complex with 3,5-dinitrobenzoic acid and ethylenediamine"],"prefix":"10.1107","volume":"76","author":[{"given":"Avazbek","family":"Ibragimov","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jamshid","family":"Ashurov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Aziz","family":"Dusmatov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Aziz","family":"Ibragimov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,6,19]]},"reference":[{"key":"yk2132_bb1","doi-asserted-by":"crossref","first-page":"1250","DOI":"10.1016\/j.ijleo.2012.03.005","volume":"124","author":"Chandrasekaran","year":"2013","journal-title":"Optik"},{"key":"yk2132_bb2","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1016\/j.molstruc.2013.09.009","volume":"1053","author":"Dey","year":"2013","journal-title":"J. Mol. Struct."},{"key":"yk2132_bb3","unstructured":"Elks, E. J. & Ganellin, C. R. (1990). Editors. Dictionary of Drugs, p. 445. London: Chapman & Hall."},{"key":"yk2132_bb4","doi-asserted-by":"crossref","first-page":"120","DOI":"10.1021\/ar00172a005","volume":"23","author":"Etter","year":"1990","journal-title":"Acc. Chem. Res."},{"key":"yk2132_bb5","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"yk2132_bb6","first-page":"45","volume":"1","author":"Ibragimov","year":"2020","journal-title":"Rep. Uzbek. Acad. Sci."},{"key":"yk2132_bb7","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1134\/S1070328417060021","volume":"43","author":"Ibragimov","year":"2017","journal-title":"Russ. J. Coord. Chem."},{"key":"yk2132_bb8","doi-asserted-by":"crossref","first-page":"352","DOI":"10.1007\/s10870-016-0665-8","volume":"46","author":"Ibragimov","year":"2016","journal-title":"J. Chem. Crystallogr."},{"key":"yk2132_bb14","doi-asserted-by":"crossref","first-page":"875","DOI":"10.3109\/03639045.2014.971027","volume":"41","author":"Jain","year":"2015","journal-title":"Drug Dev. Ind. Pharm."},{"key":"yk2132_bb9","doi-asserted-by":"crossref","first-page":"o1823","DOI":"10.1107\/S1600536805015333","volume":"61","author":"Jones","year":"2005","journal-title":"Acta Cryst. E"},{"key":"yk2132_bb10","unstructured":"Lewinska, I., Michalec, M. & Tymecki, L. (2018). Proceedings of the 14th International Students Conference `Modern Analytical Chemistry', Prague, pp. 145-151."},{"key":"yk2132_bb11","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1107\/S1600576719014092","volume":"53","author":"Macrae","year":"2020","journal-title":"J. Appl. Cryst."},{"key":"yk2132_bb12","doi-asserted-by":"crossref","first-page":"1787","DOI":"10.1016\/S0379-6779(98)01161-8","volume":"102","author":"Matsushita","year":"1999","journal-title":"Synth. Met."},{"key":"yk2132_bb13","doi-asserted-by":"crossref","first-page":"2207","DOI":"10.1107\/S0108270192004190","volume":"48","author":"Nethaji","year":"1992","journal-title":"Acta Cryst. C"},{"key":"yk2132_bb15","unstructured":"Rigaku OD (2015). CrysAlis PRO. Rigaku Oxford Diffraction, Yarnton, England."},{"key":"yk2132_bb16","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"yk2132_bb17","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"yk2132_bb18","doi-asserted-by":"crossref","first-page":"3348","DOI":"10.1021\/acs.cgd.9b00246","volume":"19","author":"Torres","year":"2019","journal-title":"Cryst. Growth Des."},{"key":"yk2132_bb19","doi-asserted-by":"crossref","first-page":"art1594","DOI":"10.3389\/fmicb.2018.01594","volume":"9","author":"Turecka","year":"2018","journal-title":"Front. Microbiol."},{"key":"yk2132_bb20","unstructured":"Turner, M. J., McKinnon, J. J., Wolff, S. K., Grimwood, D. J., Spackman, P. R., Jayatilaka, D. & Spackman, M. A. (2017). CrystalExplorer17.5. University of Western Australia. http:\/\/hirshfeldsurface.net."},{"key":"yk2132_bb21","first-page":"77","volume":"2","author":"Vaskova","year":"2009","journal-title":"Acta Chim. Slovac."},{"key":"yk2132_bb22","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2020\/07\/00\/yk2132\/yk2132.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2020\/07\/00\/yk2132\/yk2132.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T11:11:04Z","timestamp":1736766664000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989020007938"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,6,19]]},"references-count":22,"journal-issue":{"issue":"7","published-online":{"date-parts":[[2020,7]]}},"alternative-id":["S2056989020007938"],"URL":"https:\/\/doi.org\/10.1107\/s2056989020007938","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989020007938\/yk2132sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989020007938\/yk2132Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,6,19]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?yk2132","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"27 May 2020","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"11 June 2020","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"19 June 2020","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?yk2132"}},{"value":"\u00a9 2020 Ibragimov et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}