{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:13Z","timestamp":1740174553408,"version":"3.37.3"},"reference-count":39,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2020,9,22]],"date-time":"2020-09-22T00:00:00Z","timestamp":1600732800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2020,9,22]],"date-time":"2020-09-22T00:00:00Z","timestamp":1600732800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"National Science Foundation","award":["EAR \u2013 1651017"],"award-info":[{"award-number":["EAR \u2013 1651017"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2020,9,17]]},"published-print":{"date-parts":[[2020,10,1]]},"abstract":"<jats:p>The structural properties of cobalt phosphides were investigated at high pressures and temperatures to better understand the behavior of metal-rich phosphides in Earth and planetary interiors. Using single-crystal X-ray diffraction synchrotron data and a laser-heated diamond anvil cell, we discovered a new high pressure\u2013temperature (<jats:italic>HP\u2013HT<\/jats:italic>) cobalt phosphide, Co<jats:sub>12<\/jats:sub>P<jats:sub>7<\/jats:sub>, dodecacobalt heptaphosphide, synthesized at 27\u2005GPa and 1740\u2005K, and at 48\u2005GPa and 1790\u2005K. Co<jats:sub>12<\/jats:sub>P<jats:sub>7<\/jats:sub> adopts a structure initially proposed for Cr<jats:sub>12<\/jats:sub>P<jats:sub>7<\/jats:sub> (space-group type <jats:italic>P<\/jats:italic>\\overline{6}, <jats:italic>Z<\/jats:italic> =1), consisting of chains of edge-sharing CoP<jats:sub>5<\/jats:sub> square pyramids and chains of corner-sharing CoP<jats:sub>4<\/jats:sub> tetrahedra. This arrangement leaves space for trigonal\u2013prismatic channels running parallel to the <jats:italic>c<\/jats:italic> axis. Coupled disordering of metal and phosphorus atoms has been observed in this structure for related <jats:italic>M<\/jats:italic>\n                  <jats:sub>12<\/jats:sub>P<jats:sub>7<\/jats:sub> (<jats:italic>M<\/jats:italic> = Cr, V) compounds, but all Co and P sites are ordered in Co<jats:sub>12<\/jats:sub>P<jats:sub>7<\/jats:sub>. All atomic sites in this crystal structure are situated on special positions. Upon decompression to ambient conditions, peak broadening and loss of reflections at high angles was observed, suggesting phase instability.<\/jats:p>","DOI":"10.1107\/s2056989020012657","type":"journal-article","created":{"date-parts":[[2020,9,22]],"date-time":"2020-09-22T08:13:52Z","timestamp":1600762432000},"page":"1665-1668","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["The novel high-pressure\/high-temperature compound Co<sub>12<\/sub>P<sub>7<\/sub> determined from synchrotron data"],"prefix":"10.1107","volume":"76","author":[{"given":"Claire","family":"Zurkowski","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8556-7916","authenticated-orcid":true,"given":"Barbara","family":"Lavina","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Stella","family":"Chariton","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sergey","family":"Tkachev","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9270-2330","authenticated-orcid":true,"given":"Vitali","family":"Prakapenka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrew","family":"Campbell","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,9,22]]},"reference":[{"key":"wm5583_bb1","doi-asserted-by":"crossref","first-page":"373","DOI":"10.1007\/BF00909330","volume":"102","author":"Baurecht","year":"1971","journal-title":"Monats. Chem."},{"key":"wm5583_bb2","doi-asserted-by":"crossref","first-page":"556","DOI":"10.1016\/j.epsl.2009.07.022","volume":"286","author":"Campbell","year":"2009","journal-title":"Earth Planet. Sci. Lett."},{"key":"wm5583_bb3","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1016\/j.pepi.2007.04.001","volume":"162","author":"Campbell","year":"2007","journal-title":"Phys. Earth Planet. Inter."},{"key":"wm5583_bb4","doi-asserted-by":"crossref","first-page":"30","DOI":"10.1107\/S0567740879002466","volume":"35","author":"Chun","year":"1979","journal-title":"Acta Cryst. B"},{"key":"wm5583_bb5","doi-asserted-by":"crossref","first-page":"l10301","DOI":"10.1029\/2008GL033867","volume":"35","author":"Dera","year":"2008","journal-title":"Geophys. Res. Lett."},{"key":"wm5583_bb6","doi-asserted-by":"crossref","first-page":"4351","DOI":"10.1088\/0953-8984\/8\/24\/004","volume":"8","author":"Dhahri","year":"1996","journal-title":"J. Phys. Condens. Matter"},{"key":"wm5583_bb7","doi-asserted-by":"crossref","first-page":"2257","DOI":"10.1002\/1521-3749(200109)627:9<2257::AID-ZAAC2257>3.0.CO;2-W","volume":"627","author":"Ellner","year":"2001","journal-title":"Z. Anorg. Allg. Chem."},{"key":"wm5583_bb8","doi-asserted-by":"crossref","first-page":"9182","DOI":"10.1073\/pnas.0609013104","volume":"104","author":"Fei","year":"2007","journal-title":"PNAS"},{"key":"wm5583_bb9","doi-asserted-by":"crossref","unstructured":"Fujii, S., Ishida, S. & Asano, S. (1988). J. Phys. F: Met. Phys. 18, 971-980.","DOI":"10.1088\/0305-4608\/18\/5\/014"},{"key":"wm5583_bb10","doi-asserted-by":"crossref","first-page":"502","DOI":"10.1107\/S0365110X65001081","volume":"18","author":"Hamilton","year":"1965","journal-title":"Acta Cryst."},{"key":"wm5583_bb11","first-page":"113","volume":"2","author":"Heinz","year":"1987","journal-title":"High Press. Res. Miner. Phys."},{"key":"wm5583_bb12","doi-asserted-by":"crossref","first-page":"309","DOI":"10.1016\/0022-4596(78)90116-0","volume":"25","author":"Jeitschko","year":"1978","journal-title":"J. Solid State Chem."},{"key":"wm5583_bb13","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1002\/zaac.19804670112","volume":"467","author":"Jeitschko","year":"1980","journal-title":"Z. Anorg. Allg. Chem."},{"key":"wm5583_bb14","doi-asserted-by":"crossref","first-page":"331","DOI":"10.1016\/0022-4596(84)90286-X","volume":"55","author":"Jeitschko","year":"1984","journal-title":"J. Solid State Chem."},{"key":"wm5583_bb15","doi-asserted-by":"crossref","first-page":"392","DOI":"10.1107\/S0021889890005635","volume":"23","author":"Loveday","year":"1990","journal-title":"J. Appl. Cryst."},{"key":"wm5583_bb16","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1016\/0022-4596(81)90372-8","volume":"40","author":"Maaref","year":"1981","journal-title":"J. Solid State Chem."},{"key":"wm5583_bb17","doi-asserted-by":"crossref","first-page":"851","DOI":"10.1126\/science.191.4229.851","volume":"191","author":"Mao","year":"1976","journal-title":"Science"},{"key":"wm5583_bb18","doi-asserted-by":"crossref","first-page":"1272","DOI":"10.1107\/S0021889811038970","volume":"44","author":"Momma","year":"2011","journal-title":"J. Appl. Cryst."},{"key":"wm5583_bb19","unstructured":"Okamoto, H. & Massalski, T. B. (1990). Editors. Binary Alloy Phase Diagrams. OH, USA: ASM International."},{"key":"wm5583_bb20","doi-asserted-by":"crossref","first-page":"2389","DOI":"10.3891\/acta.chem.scand.24-2389","volume":"24","author":"Olofsson","year":"1970","journal-title":"Acta Chem. Scand."},{"key":"wm5583_bb21","doi-asserted-by":"crossref","first-page":"1941","DOI":"10.2138\/am.2006.2347","volume":"91","author":"Ono","year":"2006","journal-title":"Am. Mineral."},{"key":"wm5583_bb22","doi-asserted-by":"crossref","first-page":"481","DOI":"10.1016\/j.epsl.2008.05.017","volume":"272","author":"Ono","year":"2008","journal-title":"Earth Planet. Sci. Lett."},{"key":"wm5583_bb23","doi-asserted-by":"crossref","first-page":"4745","DOI":"10.1039\/C6TA00575F","volume":"4","author":"Pan","year":"2016","journal-title":"J. Mater. Chem. A"},{"key":"wm5583_bb24","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1107\/S2052519213010014","volume":"69","author":"Parsons","year":"2013","journal-title":"Acta Cryst. B"},{"key":"wm5583_bb25","doi-asserted-by":"crossref","first-page":"5531","DOI":"10.1002\/ange.201402646","volume":"126","author":"Popczun","year":"2014","journal-title":"Angew. Chem."},{"key":"wm5583_bb26","doi-asserted-by":"crossref","first-page":"13693","DOI":"10.1002\/ange.201707878","volume":"129","author":"Pramanik","year":"2017","journal-title":"Angew. Chem."},{"key":"wm5583_bb27","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1080\/08957959.2015.1059835","volume":"35","author":"Prescher","year":"2015","journal-title":"High. Press. Res."},{"key":"wm5583_bb28","doi-asserted-by":"crossref","first-page":"1413","DOI":"10.1007\/s10562-012-0929-7","volume":"142","author":"Prins","year":"2012","journal-title":"Catal. Lett."},{"key":"wm5583_bb29","doi-asserted-by":"crossref","first-page":"563","DOI":"10.1016\/0022-3697(89)90448-4","volume":"50","author":"Reehuis","year":"1989","journal-title":"J. Phys. Chem. Solids"},{"key":"wm5583_bb30","unstructured":"Rigaku OD (2018). CrysAlis PRO. Rigaku Oxford Diffraction Ltd, Yarnton, England."},{"key":"wm5583_bb31","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1080\/08957950802333593","volume":"28","author":"Rivers","year":"2008","journal-title":"High Pressure Res."},{"key":"wm5583_bb32","doi-asserted-by":"crossref","first-page":"1961","DOI":"10.3891\/acta.chem.scand.14-1961","volume":"14","author":"Rundqvist","year":"1960","journal-title":"Acta Chem. Scand."},{"key":"wm5583_bb33","doi-asserted-by":"crossref","first-page":"1","DOI":"10.3891\/acta.chem.scand.16-0001","volume":"16","author":"Rundqvist","year":"1962","journal-title":"Acta Chem. Scand."},{"key":"wm5583_bb34","doi-asserted-by":"crossref","first-page":"4267","DOI":"10.1021\/cr000039m","volume":"102","author":"Schlesinger","year":"2002","journal-title":"Chem. Rev."},{"key":"wm5583_bb35","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"wm5583_bb36","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"wm5583_bb37","doi-asserted-by":"crossref","first-page":"11944","DOI":"10.1029\/2019GL085248","volume":"46","author":"Tateno","year":"2019","journal-title":"Geophys. Res. Lett."},{"key":"wm5583_bb38","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"wm5583_bb39","doi-asserted-by":"crossref","first-page":"288","DOI":"10.1107\/S0365110X49000746","volume":"2","author":"Zachariasen","year":"1949","journal-title":"Acta Cryst."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2020\/10\/00\/wm5583\/wm5583.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2020\/10\/00\/wm5583\/wm5583.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:22:48Z","timestamp":1736763768000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989020012657"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,9,22]]},"references-count":39,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2020,10]]}},"alternative-id":["S2056989020012657"],"URL":"https:\/\/doi.org\/10.1107\/s2056989020012657","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989020012657\/wm5583sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989020012657\/wm5583Co12P7_at_48GPasup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989020012657\/wm5583Co12P7_at_15GPasup3.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2020,9,22]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?wm5583","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"10 August 2020","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"17 September 2020","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"22 September 2020","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5583"}},{"value":"\u00a9 2020 Zurkowski et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}