{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,5]],"date-time":"2025-11-05T21:08:05Z","timestamp":1762376885017,"version":"3.37.3"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2021,2,26]],"date-time":"2021-02-26T00:00:00Z","timestamp":1614297600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2021,2,26]],"date-time":"2021-02-26T00:00:00Z","timestamp":1614297600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"National Science Foundation","award":["CHE-1900541"],"award-info":[{"award-number":["CHE-1900541"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2021,2,23]]},"published-print":{"date-parts":[[2021,3,1]]},"abstract":"<jats:p>The title compound, [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>19<\/jats:sub>H<jats:sub>23<\/jats:sub>N<jats:sub>7<\/jats:sub>O)(C<jats:sub>2<\/jats:sub>H<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, was obtained <jats:italic>via<\/jats:italic> reaction of copper(II) acetate with the coordinating ligand, 6-ethoxy-<jats:italic>N<\/jats:italic>\n                  <jats:sup>2<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>4<\/jats:sup>-bis[2-(pyridin-2-yl)ethyl]-1,3,5-triazine-2,4-diamine. The crystallized product adopts the monoclinic <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic> space group. The metal core exhibits a paddle-wheel structure typical for dicopper tetraacetate units, with triazine and pyridyl nitrogen atoms from different ligands coordinating to the two axial positions of the paddle wheel in an asymmetric manner. This forms a coordination polymer with the segments of the polymer created by the <jats:italic>c<\/jats:italic>-glide of the <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic> setting of the space group. The resulting chains running along the <jats:italic>c<\/jats:italic>-axis direction are held together by intramolecular N\u2014H...O hydrogen bonding. These chains are further packed by dispersion forces, producing an extended three-dimensional structure.<\/jats:p>","DOI":"10.1107\/s2056989021002164","type":"journal-article","created":{"date-parts":[[2021,2,26]],"date-time":"2021-02-26T09:52:54Z","timestamp":1614333174000},"page":"319-323","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis and crystal structure of <i>catena<\/i>-poly[[tetra-\u03bc-acetato-copper(II)]-\u03bc-6-ethoxy-<i>N<\/i>\n                  <sup>2<\/sup>,<i>N<\/i>\n                  <sup>4<\/sup>-bis[2-(pyridin-2-yl)ethyl]-1,3,5-triazine-2,4-diamine]"],"prefix":"10.1107","volume":"77","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7954-5403","authenticated-orcid":true,"given":"Mayokun J.","family":"Ayodele","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Travis C.","family":"Green","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"W. 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