{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,9]],"date-time":"2025-11-09T07:47:56Z","timestamp":1762674476574,"version":"3.37.3"},"reference-count":28,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2021,4,9]],"date-time":"2021-04-09T00:00:00Z","timestamp":1617926400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2021,4,9]],"date-time":"2021-04-09T00:00:00Z","timestamp":1617926400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100001501","name":"University Grants Commission","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001501","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2021,4,5]]},"published-print":{"date-parts":[[2021,5,1]]},"abstract":"<jats:p>The title compound, [ZnCl<jats:sub>2<\/jats:sub>(C<jats:sub>13<\/jats:sub>H<jats:sub>11<\/jats:sub>N<jats:sub>3<\/jats:sub>)]\u00b7C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>NO, crystallized in the monoclinic crystal system in space group <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>n<\/jats:italic>. The asymmetric unit contains one neutral complex molecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with dimethylformamide monosolvate. The ligand has two moieties, a benzimidazole and an aniline group. The benzimidazole and aniline planes are not coplanar, subtending a dihedral angle of 18.24\u2005(8)\u00b0. The Zn(II) ion shows distorted tetrahedral geometry, being coordinated by an imidazole N atom, the aniline N atom, and two chlorido ligands. The packing features N\u2014H...O, N\u2014H...Cl, C\u2014H...Cl hydrogen bonding.<\/jats:p>","DOI":"10.1107\/s2056989021003649","type":"journal-article","created":{"date-parts":[[2021,4,9]],"date-time":"2021-04-09T08:10:36Z","timestamp":1617955836000},"page":"491-494","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure and Hirshfeld surface analysis of [2-(1<i>H<\/i>-benzimidazol-2-yl-\u03ba<i>N<\/i>\n                  <sup>3<\/sup>)aniline-\u03ba<i>N<\/i>]dichloridozinc(II) <i>N<\/i>,<i>N<\/i>-dimethylformamide monosolvate"],"prefix":"10.1107","volume":"77","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5071-6942","authenticated-orcid":true,"given":"Mohd","family":"Muslim","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4678-9508","authenticated-orcid":true,"given":"Md. 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