{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,25]],"date-time":"2026-03-25T11:35:43Z","timestamp":1774438543363,"version":"3.50.1"},"reference-count":33,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2021,4,23]],"date-time":"2021-04-23T00:00:00Z","timestamp":1619136000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2021,4,23]],"date-time":"2021-04-23T00:00:00Z","timestamp":1619136000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100001691","name":"KAKENHI","doi-asserted-by":"crossref","award":["20H00336"],"award-info":[{"award-number":["20H00336"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2021,4,5]]},"published-print":{"date-parts":[[2021,5,1]]},"abstract":"<jats:p>The compound, {6,6\u2032-dimethoxy-2,2\u2032-[(4-azaheptane-1,7-diyl)bis(nitrilomethanylidyne)]diphenolato}zinc(II) methanol monosolvate, [Zn(C<jats:sub>22<\/jats:sub>H<jats:sub>27<\/jats:sub>N<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub>)]\u00b7CH<jats:sub>3<\/jats:sub>OH, at 298\u2005K crystallizes in the orthorhombic space group P<jats:italic>na<\/jats:italic>2<jats:sub>1<\/jats:sub>. The Zn atom is coordinated by a pentadentate Schiff base ligand in a distorted trigonal\u2013bipyramidal N<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub> geometry. The equatorial plane is formed by the two phenolic O and one amine N atom. The axial positions are occupied by two amine N atoms. The distorted bipyramidal geometry is also supported by the trigonality index (\u03c4), which is found to be 0.85 for the molecule. In the crystal, methanol solvent molecule is connected to the complex molecule by an O\u2014H...O hydrogen bond and the complex molecules are connected by weak supramolecular interactions, so achiral molecules generate a chiral crystal. The Hirshfeld surface analysis suggests that H...H contacts account for the largest percentage of all interactions.<\/jats:p>","DOI":"10.1107\/s2056989021003650","type":"journal-article","created":{"date-parts":[[2021,4,23]],"date-time":"2021-04-23T10:15:27Z","timestamp":1619172927000},"page":"542-546","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Chiral crystallization of a zinc(II) complex"],"prefix":"10.1107","volume":"77","author":[{"given":"Shabana","family":"Noor","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shintaro","family":"Suda","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5772-9754","authenticated-orcid":true,"given":"Tomoyuki","family":"Haraguchi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fehmeeda","family":"Khatoon","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Takashiro","family":"Akitsu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2021,4,23]]},"reference":[{"key":"jy2006_bb21","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"jy2006_bb1","doi-asserted-by":"crossref","first-page":"m324","DOI":"10.1107\/S0108270105013545","volume":"61","author":"Akitsu","year":"2005","journal-title":"Acta Cryst. C"},{"key":"jy2006_bb2","doi-asserted-by":"crossref","first-page":"411","DOI":"10.1007\/s10870-016-0670-y","volume":"46","author":"AlDamen","year":"2016","journal-title":"J. Chem. Crystallogr."},{"key":"jy2006_bb3","doi-asserted-by":"crossref","first-page":"1221","DOI":"10.1007\/s10973-017-6563-2","volume":"131","author":"Bartyzel","year":"2018","journal-title":"J. Therm. Anal. Calorim."},{"key":"jy2006_bb4","doi-asserted-by":"crossref","first-page":"3789","DOI":"10.1002\/ejic.200700199","author":"Bermejo","year":"2007","journal-title":"Eur. J. Inorg. Chem."},{"key":"jy2006_bb5","unstructured":"Bruker (2017). APEX3, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"jy2006_bb6","doi-asserted-by":"crossref","first-page":"715","DOI":"10.1007\/s11243-013-9741-5","volume":"38","author":"Fleck","year":"2013","journal-title":"Transition Met. Chem."},{"key":"jy2006_bb7","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"jy2006_bb8","doi-asserted-by":"crossref","first-page":"1281","DOI":"10.1107\/S0021889811043202","volume":"44","author":"H\u00fcbschle","year":"2011","journal-title":"J. Appl. Cryst."},{"key":"jy2006_bb9","doi-asserted-by":"crossref","unstructured":"Iksi, S., Guemmout, F. E., Reguero, M., Masdeu-Bulto, A. M. & Ghnux, A. (2020). J Chem Crystallogr. https:\/\/doi.org\/10.1007\/s10870-020-00865-y.","DOI":"10.1007\/s10870-020-00865-y"},{"key":"jy2006_bb10","doi-asserted-by":"crossref","first-page":"8694","DOI":"10.1021\/ja029629n","volume":"125","author":"Ishikawa","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"jy2006_bb11","doi-asserted-by":"crossref","first-page":"m536","DOI":"10.1107\/S1600536811012049","volume":"67","author":"Jing","year":"2011","journal-title":"Acta Cryst. E"},{"key":"jy2006_bb12","doi-asserted-by":"crossref","first-page":"518","DOI":"10.1134\/S1070328411070074","volume":"37","author":"Khalaji","year":"2011","journal-title":"Russ. J. Coord. Chem."},{"key":"jy2006_bb13","doi-asserted-by":"crossref","first-page":"829","DOI":"10.1107\/S0567740881004433","volume":"37","author":"Korhonen","year":"1981","journal-title":"Acta Cryst. B"},{"key":"jy2006_bb14","doi-asserted-by":"crossref","first-page":"8819","DOI":"10.1002\/adma.201601133","volume":"28","author":"Li","year":"2016","journal-title":"Adv. Mater."},{"key":"jy2006_bb15","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1016\/j.ccr.2018.02.019","volume":"363","author":"Long","year":"2018","journal-title":"Coord. Chem. Rev."},{"key":"jy2006_bb16","doi-asserted-by":"crossref","unstructured":"Lui, W., Li, G., Zhao, X. & Wang, L. (2019). ChemistrySelect, 4, 29, 9317-9321.","DOI":"10.1002\/slct.201902139"},{"key":"jy2006_bb17","doi-asserted-by":"crossref","first-page":"850","DOI":"10.1016\/j.arabjc.2012.12.039","volume":"8","author":"Matar","year":"2015","journal-title":"Arab. J. Chem."},{"key":"jy2006_bb19","unstructured":"Niu, M. J., Li, Z., Chang, G. L., Kong, X. J., Hong, M. & Zhang, Q. F. (2015). PLOS ONE. https:\/\/doi.org\/10.1317\/journal.pone.0130922."},{"key":"jy2006_bb20","doi-asserted-by":"crossref","first-page":"164","DOI":"10.1007\/s10870-018-0724-4","volume":"48","author":"Noor","year":"2018","journal-title":"J. Chem. Crystallogr."},{"key":"jy2006_bb22","doi-asserted-by":"crossref","unstructured":"Noor, S. W., Seidel, R. W., Goddard, R., Kumar, S. & Sabir, S. (2016). IUCrData, 1, x161735.","DOI":"10.1107\/S2414314616017351"},{"key":"jy2006_bb23","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1107\/S2052519213010014","volume":"69","author":"Parsons","year":"2013","journal-title":"Acta Cryst. B"},{"key":"jy2006_bb24","doi-asserted-by":"crossref","first-page":"m745","DOI":"10.1107\/S1600536808012191","volume":"64","author":"Qiu","year":"2008","journal-title":"Acta Cryst. E"},{"key":"jy2006_bb25","doi-asserted-by":"crossref","first-page":"126","DOI":"10.1016\/S0010-8545(00)80165-4","volume":"1","author":"Sacconi","year":"1966","journal-title":"Coord. Chem. Rev."},{"key":"jy2006_bb26","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1016\/S0020-1693(01)00407-8","volume":"318","author":"Sanmart\u00edn","year":"2001","journal-title":"Inorg. Chim. Acta"},{"key":"jy2006_bb27","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"jy2006_bb28","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"jy2006_bb29","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"jy2006_bb30","doi-asserted-by":"crossref","first-page":"206","DOI":"10.3390\/11020206","volume":"11","author":"Siddiqui","year":"2006","journal-title":"Molecules"},{"key":"jy2006_bb31","doi-asserted-by":"crossref","first-page":"19","DOI":"10.1039\/B818330A","volume":"11","author":"Spackman","year":"2009","journal-title":"CrystEngComm"},{"key":"jy2006_bb32","doi-asserted-by":"crossref","first-page":"8069","DOI":"10.1039\/c3ce41034j","volume":"15","author":"Tang","year":"2013","journal-title":"CrystEngComm"},{"key":"jy2006_bb18","doi-asserted-by":"crossref","first-page":"1395","DOI":"10.1016\/j.ica.2009.12.053","volume":"336","author":"Thakurta","year":"2010","journal-title":"Inorg. Chim. Acta"},{"key":"jy2006_bb33","unstructured":"Turner, M. J., Mckinnon, J. J., Wolff, S. K., Grimwood, D. J., Spackman, P. R., Jayatilaka, D. & Spackman, M. A. (2017). CrystalExplorer17. University of Western Australia."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2021\/05\/00\/jy2006\/jy2006.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2021\/05\/00\/jy2006\/jy2006.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:33:03Z","timestamp":1736764383000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989021003650"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,4,23]]},"references-count":33,"journal-issue":{"issue":"5","published-online":{"date-parts":[[2021,5]]}},"alternative-id":["S2056989021003650"],"URL":"https:\/\/doi.org\/10.1107\/s2056989021003650","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989021003650\/jy2006sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989021003650\/jy2006Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,4,23]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?jy2006","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"10 March 2021","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"5 April 2021","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"23 April 2021","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?jy2006"}},{"value":"\u00a9 2021 Noor et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}