{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,10]],"date-time":"2026-01-10T21:25:25Z","timestamp":1768080325156,"version":"3.49.0"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2021,5,7]],"date-time":"2021-05-07T00:00:00Z","timestamp":1620345600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2021,5,7]],"date-time":"2021-05-07T00:00:00Z","timestamp":1620345600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2021,4,28]]},"published-print":{"date-parts":[[2021,6,1]]},"abstract":"<jats:p>The crystal structure of magnesium zinc divanadate, MgZnV<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>, was determined and refined from laboratory X-ray powder diffraction data. The title compound was synthesized by a solid-state reaction at 1023\u2005K in air. The crystal structure is isotypic with Mn<jats:sub>0.6<\/jats:sub>Zn<jats:sub>1.4<\/jats:sub>V<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub> (<jats:italic>C2<\/jats:italic>\/<jats:italic>m<\/jats:italic>; <jats:italic>Z<\/jats:italic> = 6) and is related to the crystal structure of thortveitite. The asymmetric unit contains two metal sites with statistically distributed magnesium and zinc atoms with the atomic ratio close to 1:1. One (Mg\/Zn) metal site (<jats:italic>M<\/jats:italic>1) is located on Wyckoff position 8<jats:italic>j<\/jats:italic> and the other (<jats:italic>M<\/jats:italic>2) on 4<jats:italic>h<\/jats:italic>. Three V sites (all on 4<jats:italic>i<\/jats:italic>), and eight O (three 8<jats:italic>j<\/jats:italic>, four 4<jats:italic>i<\/jats:italic>, and one 2<jats:italic>b<\/jats:italic>) sites complete the asymmetric unit. The structure is an alternate stacking of V<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub> layers and (Mg\/Zn) atom layers along [20\\overline{1}]. It is distinct from other related structures in that each V<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub> layer consists of two groups: a V<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub> dimer and a V<jats:sub>4<\/jats:sub>O<jats:sub>14<\/jats:sub> tetramer. Mixed-occupied <jats:italic>M<\/jats:italic>1 and <jats:italic>M<\/jats:italic>2 are coordinated by oxygen atoms in distorted trigonal bipyramidal and octahedral sites, respectively.<\/jats:p>","DOI":"10.1107\/s2056989021004503","type":"journal-article","created":{"date-parts":[[2021,5,7]],"date-time":"2021-05-07T07:47:16Z","timestamp":1620373636000},"page":"588-591","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure refinement of magnesium zinc divanadate, MgZnV<sub>2<\/sub>O<sub>7<\/sub>, from powder X-ray diffraction data"],"prefix":"10.1107","volume":"77","author":[{"given":"Stephanie J.","family":"Hong","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6911-4474","authenticated-orcid":true,"given":"Jun","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5487-043X","authenticated-orcid":true,"given":"Mas A.","family":"Subramanian","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2021,5,7]]},"reference":[{"key":"wm5602_bb1","doi-asserted-by":"crossref","first-page":"1487","DOI":"10.1107\/S0021889803021800","volume":"36","author":"Betteridge","year":"2003","journal-title":"J. Appl. Cryst."},{"key":"wm5602_bb2","doi-asserted-by":"crossref","first-page":"724","DOI":"10.1107\/S0021889804014876","volume":"37","author":"Boultif","year":"2004","journal-title":"J. Appl. Cryst."},{"key":"wm5602_bb3","doi-asserted-by":"crossref","first-page":"192","DOI":"10.1107\/S0108768190011041","volume":"47","author":"Brese","year":"1991","journal-title":"Acta Cryst. B"},{"key":"wm5602_bb4","doi-asserted-by":"crossref","first-page":"244","DOI":"10.1107\/S0108768185002063","volume":"41","author":"Brown","year":"1985","journal-title":"Acta Cryst. B"},{"key":"wm5602_bb5","doi-asserted-by":"crossref","first-page":"689","DOI":"10.1111\/j.1151-2916.1988.tb06389.x","volume":"71","author":"Chang","year":"1988","journal-title":"J. Am. Ceram. Soc."},{"key":"wm5602_bb6","doi-asserted-by":"crossref","first-page":"1004","DOI":"10.1139\/v73-149","volume":"51","author":"Gopal","year":"1973","journal-title":"Can. J. Chem."},{"key":"wm5602_bb7","doi-asserted-by":"crossref","first-page":"2491","DOI":"10.1107\/S0567740874007400","volume":"30","author":"Gopal","year":"1974","journal-title":"Acta Cryst. B"},{"key":"wm5602_bb8","unstructured":"Hormillosa, C., Healy, S., Stephen, T. & Brown, I. D. (1993). Bond Valence Calculator. Version 2.0. McMaster University, Canada."},{"key":"wm5602_bb9","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1006\/jssc.1994.1163","volume":"110","author":"Huang","year":"1994","journal-title":"J. Solid State Chem."},{"key":"wm5602_bb10","doi-asserted-by":"crossref","first-page":"1079","DOI":"10.1107\/S2053229618010458","volume":"74","author":"Knowles","year":"2018","journal-title":"Acta Cryst. C"},{"key":"wm5602_bb11","doi-asserted-by":"crossref","first-page":"160","DOI":"10.1107\/S0108768108042444","volume":"65","author":"Knowles","year":"2009","journal-title":"Acta Cryst. B"},{"key":"wm5602_bb12","first-page":"40","volume":"48","author":"Krasnenko","year":"2003","journal-title":"Kristallografiya"},{"key":"wm5602_bb13","unstructured":"Larson, A. C. & Von Dreele, R. B. (2000). General Structure Analysis System (GSAS). Report LAUR. 86-748 Los Alamos National Laboratory, New Mexico, USA."},{"key":"wm5602_bb14","doi-asserted-by":"crossref","first-page":"305","DOI":"10.1016\/0022-4596(92)90038-W","volume":"97","author":"Launay","year":"1992","journal-title":"J. Solid State Chem."},{"key":"wm5602_bb15","doi-asserted-by":"crossref","first-page":"1272","DOI":"10.1107\/S0021889811038970","volume":"44","author":"Momma","year":"2011","journal-title":"J. Appl. Cryst."},{"key":"wm5602_bb16","doi-asserted-by":"crossref","first-page":"3214","DOI":"10.1039\/b104454k","author":"Nielsen","year":"2001","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"wm5602_bb17","unstructured":"PANalytical (2011). X'Pert Data Collector and X'Pert High Score Plus. PANalytical BV, Almelo, The Netherlands."},{"key":"wm5602_bb18","doi-asserted-by":"crossref","first-page":"600","DOI":"10.1107\/S0021889807018894","volume":"40","author":"Rohl\u00ed\u010dek","year":"2007","journal-title":"J. Appl. Cryst."},{"key":"wm5602_bb19","doi-asserted-by":"crossref","unstructured":"Roisnel, T. & Rodr\u00edguez-Carvajal, J. (2000). WinPLOTR: a Windows tool for powder diffraction patterns analysis. Mater. Sci. Forum, Proc. 7th Europ. Powder Diff. Conf. (EPDIC 7), edited by R. Delhez & E. J. Mittenmeijer, pp. 118-123.","DOI":"10.4028\/www.scientific.net\/MSF.378-381.118"},{"key":"wm5602_bb20","doi-asserted-by":"crossref","first-page":"751","DOI":"10.1107\/S0567739476001551","volume":"32","author":"Shannon","year":"1976","journal-title":"Acta Cryst. A"},{"key":"wm5602_bb21","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2021\/06\/00\/wm5602\/wm5602.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2021\/06\/00\/wm5602\/wm5602.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:33:23Z","timestamp":1736764403000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989021004503"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,5,7]]},"references-count":21,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2021,6]]}},"alternative-id":["S2056989021004503"],"URL":"https:\/\/doi.org\/10.1107\/s2056989021004503","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989021004503\/wm5602sup1.cif","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,5,7]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?wm5602","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"24 February 2021","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"28 April 2021","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"7 May 2021","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5602"}},{"value":"\u00a9 2021 Hong et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}