{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:22Z","timestamp":1740174562364,"version":"3.37.3"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2021,7,13]],"date-time":"2021-07-13T00:00:00Z","timestamp":1626134400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2021,7,13]],"date-time":"2021-07-13T00:00:00Z","timestamp":1626134400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100010798","name":"Sunway University","doi-asserted-by":"publisher","award":["GRTIN-IRG-01-2021"],"award-info":[{"award-number":["GRTIN-IRG-01-2021"]}],"id":[{"id":"10.13039\/501100010798","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2021,6,25]]},"published-print":{"date-parts":[[2021,8,1]]},"abstract":"<jats:p>The title thiourea derivative, C<jats:sub>17<\/jats:sub>H<jats:sub>19<\/jats:sub>N<jats:sub>3<\/jats:sub>OS, adopts a U-shaped conformation with the dihedral angle between the terminal aromatic rings being 73.64\u2005(5)\u00b0. The major twist in the molecule occurs about the ethane bond with the C<jats:sub>i<\/jats:sub>\u2014C<jats:sub>e<\/jats:sub>\u2014C<jats:sub>e<\/jats:sub>\u2014C<jats:sub>b<\/jats:sub> torsion angle being \u221278.12\u2005(18)\u00b0; i = imine, e = ethane and b = benzene. The configuration about the imine bond is <jats:italic>E<\/jats:italic>, the N-bound H atoms lie on opposite sides of the molecule and an intramolecular amine-N\u2014H...N(imine) hydrogen bond is evident. In the molecular packing, hydroxyl-O\u2014H...S(thione) and amine-N\u2014H...O hydrogen bonding feature within a linear, supramolecular chain. The chains are connected into a layer in the <jats:italic>ab<\/jats:italic> plane by a combination of methylene-C\u2014H...S(thione), methylene-C\u2014H...O(hydroxyl), methyl-C\u2014H...\u03c0(phenyl) and phenyl-C\u2014H...\u03c0(hydroxybenzene) interactions. The layers stack without directional interactions between them. The analysis of the calculated Hirshfeld surface highlights the presence of weak methyl-C\u2014H...O(hydroxyl) and H...H interactions in the inter-layer region. Computational chemistry indicates that dispersion energy is the major contributor to the overall stabilization of the molecular packing.<\/jats:p>","DOI":"10.1107\/s2056989021006666","type":"journal-article","created":{"date-parts":[[2021,7,13]],"date-time":"2021-07-13T15:24:02Z","timestamp":1626189842000},"page":"788-794","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["1-{(<i>E<\/i>)-[4-(4-Hydroxyphenyl)butan-2-ylidene]amino}-3-phenylthiourea: crystal structure, Hirshfeld surface analysis and computational study"],"prefix":"10.1107","volume":"77","author":[{"given":"Ming Yueh","family":"Tan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5130-8011","authenticated-orcid":true,"given":"Huey Chong","family":"Kwong","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7494-9268","authenticated-orcid":true,"given":"Karen A.","family":"Crouse","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thahira B. 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