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The resultant five-membered chelate rings are nearly planar and form a dihedral angle of 73.28\u2005(3)\u00b0. The configurations about the endocyclic- and exocyclic-imine bonds are <jats:italic>Z<\/jats:italic> and <jats:italic>E<\/jats:italic>, respectively, and that about the ethylene bond is <jats:italic>E<\/jats:italic>. The major differences in the conformations of the ligands are seen in the dihedral angles between the chelate ring and nitrobenzene rings [40.48\u2005(6) <jats:italic>cf<\/jats:italic>. 13.18\u2005(4)\u00b0] and the <jats:italic>N<\/jats:italic>-bound phenyl and nitrobenzene ring [43.23\u2005(8) and 22.64\u2005(4)\u00b0]. In the crystal, a linear supramolecular chain along the <jats:italic>b<\/jats:italic>-axis direction features amine-N\u2014H...O(nitro) hydrogen bonding. The chains assemble along the 2<jats:sub>1<\/jats:sub>-screw axis through a combination of phenyl-C\u2014H...O(nitro) and \u03c0(chelate ring)\u2013\u03c0(phenyl) contacts. The double chains are linked into a three-dimensional architecture through phenyl-C\u2014H...O(nitro) and nitro-O...\u03c0(phenyl) interactions.<\/jats:p>","DOI":"10.1107\/s2056989021007398","type":"journal-article","created":{"date-parts":[[2021,7,27]],"date-time":"2021-07-27T08:33:12Z","timestamp":1627374792000},"page":"839-846","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Bis{<i>N<\/i>\u2032-[3-(4-nitrophenyl)-1-phenylprop-2-en-1-ylidene]-<i>N<\/i>-phenylcarbamimidothioato}zinc(II): crystal structure, Hirshfeld surface analysis and computational study"],"prefix":"10.1107","volume":"77","author":[{"given":"Ming Yueh","family":"Tan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5130-8011","authenticated-orcid":true,"given":"Huey Chong","family":"Kwong","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7494-9268","authenticated-orcid":true,"given":"Karen A.","family":"Crouse","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thahira B. 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