{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:23Z","timestamp":1740174563644,"version":"3.37.3"},"reference-count":30,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2021,8,10]],"date-time":"2021-08-10T00:00:00Z","timestamp":1628553600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2021,8,10]],"date-time":"2021-08-10T00:00:00Z","timestamp":1628553600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Open Access Funding by the Publication Fund of the TU Bergakademie Freiberg"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2021,8,2]]},"published-print":{"date-parts":[[2021,9,1]]},"abstract":"<jats:p>The title compounds, C<jats:sub>23<\/jats:sub>H<jats:sub>25<\/jats:sub>Br<jats:sub>2<\/jats:sub>NO<jats:sub>2<\/jats:sub> (<jats:bold>1<\/jats:bold>) and C<jats:sub>31<\/jats:sub>H<jats:sub>29<\/jats:sub>BrN<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub> (<jats:bold>2<\/jats:bold>), crystallize in the space group <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>n<\/jats:italic> with two (<jats:bold>1-A<\/jats:bold> and <jats:bold>1-B<\/jats:bold>) and one molecules, respectively, in the asymmetric unit of the cell. The molecular conformation of these compounds is stabilized by intramolecular C\u2014H...O hydrogen bonds and C\u2014H...N or C\u2014H...\u03c0 interactions. The crystal structure of <jats:bold>1<\/jats:bold> features a relatively strong Br...O=C halogen bond, which is not observed in the case of <jats:bold>2<\/jats:bold>. Both crystal structures are characterized by the presence of C\u2014H...Br hydrogen bonds and numerous intermolecular C\u2014H...O hydrogen-bonding interactions.<\/jats:p>","DOI":"10.1107\/s205698902100788x","type":"journal-article","created":{"date-parts":[[2021,8,10]],"date-time":"2021-08-10T12:10:30Z","timestamp":1628597430000},"page":"919-923","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structures of 2-[3,5-bis(bromomethyl)-2,4,6-triethylbenzyl]isoindoline-1,3-dione and 2-{5-(bromomethyl)-3-[(1,3-dioxoisoindolin-2-yl)methyl]-2,4,6-triethylbenzyl}isoindoline-1,3-dione"],"prefix":"10.1107","volume":"77","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6398-2337","authenticated-orcid":true,"given":"Manuel","family":"Stapf","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Betty","family":"Leibiger","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9492-5909","authenticated-orcid":true,"given":"Anke","family":"Schwarzer","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Monika","family":"Mazik","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2021,8,10]]},"reference":[{"key":"zq2264_bb1","doi-asserted-by":"crossref","first-page":"10648","DOI":"10.1039\/C6OB01682K","volume":"14","author":"Amrhein","year":"2016","journal-title":"Org. 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