{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:24Z","timestamp":1740174564165,"version":"3.37.3"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2021,9,17]],"date-time":"2021-09-17T00:00:00Z","timestamp":1631836800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2021,9,17]],"date-time":"2021-09-17T00:00:00Z","timestamp":1631836800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["341687"],"award-info":[{"award-number":["341687"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2021,9,6]]},"published-print":{"date-parts":[[2021,10,1]]},"abstract":"<jats:p>The compound bis{\u03bc<jats:sub>3<\/jats:sub>-2,5-bis[<jats:italic>N<\/jats:italic>-(4-isopropylphenyl)-<jats:italic>P<\/jats:italic>,<jats:italic>P<\/jats:italic>-diphenylphosphorimidoyl]pyrrol-1-ido-\u03ba<jats:sup>3<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>:<jats:italic>N<\/jats:italic>\u2032:<jats:italic>N<\/jats:italic>\u2032\u2032}trisilver(I) trifluoromethanesulfonate deuterated benzene pentasolvate, [Ag<jats:sub>3<\/jats:sub>(C<jats:sub>46<\/jats:sub>H<jats:sub>44<\/jats:sub>N<jats:sub>3<\/jats:sub>P<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>](CF<jats:sub>3<\/jats:sub>O<jats:sub>3<\/jats:sub>S)\u00b75C<jats:sub>6<\/jats:sub>D<jats:sub>6<\/jats:sub>, (I), was synthesized  from two equivalents of Na<jats:italic>L<\/jats:italic> [<jats:italic>L<\/jats:italic> = 2,5-(4-<jats:sup>\n                     <jats:italic>i<\/jats:italic>\n                  <\/jats:sup>PrC<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>N=PPh<jats:sub>2<\/jats:sub>)C<jats:sub>4<\/jats:sub>H<jats:sub>2<\/jats:sub>N] and three equivalents of AgOTf (OTf = OSO<jats:sub>2<\/jats:sub>CF<jats:sub>3<\/jats:sub>). High-quality crystals of (I) formed with five deuterated benzene solvent molecules in the asymmetric unit. Notably, the bond lengths and angles between the three silver atoms are markedly different, unlike in most other reported trisilver complexes that tend to form three equivalent metal centers. Additionally, to the best of our knowledge, this is the first report of a trisilver complex with six nitrogen donors from two bisphosphinimine ligands.<\/jats:p>","DOI":"10.1107\/s2056989021009221","type":"journal-article","created":{"date-parts":[[2021,9,17]],"date-time":"2021-09-17T05:41:07Z","timestamp":1631857267000},"page":"1025-1028","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["X-ray crystal structure of [<i>L<\/i>\n                  <sub>2<\/sub>Ag<sub>3<\/sub>]<sup>+<\/sup>[OTf]<sup>\u2212<\/sup>\u00b75C<sub>6<\/sub>D<sub>6<\/sub>: a monoanionic bisphosphinimine ligand supported trisilver complex"],"prefix":"10.1107","volume":"77","author":[{"given":"Sam L.","family":"Drescher","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christopher P.","family":"Forfar","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1855-360X","authenticated-orcid":true,"given":"Ren\u00e9 T.","family":"Boer\u00e9","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6882-7897","authenticated-orcid":true,"given":"Paul G.","family":"Hayes","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2021,9,17]]},"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2021\/10\/00\/zv2008\/zv2008.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2021\/10\/00\/zv2008\/zv2008.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:31:03Z","timestamp":1736764263000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989021009221"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,9,17]]},"references-count":0,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2021,10]]}},"alternative-id":["S2056989021009221"],"URL":"https:\/\/doi.org\/10.1107\/s2056989021009221","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989021009221\/zv2008sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989021009221\/zv2008Isup7.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2021,9,17]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?zv2008","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"16 June 2021","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"6 September 2021","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"17 September 2021","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?zv2008"}},{"value":"\u00a9 2021 Drescher et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}