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Two molecules of the monodeprotonated ligands coordinate the Cu<jats:sup>II<\/jats:sup> ion in an (<jats:italic>N<\/jats:italic>,<jats:italic>O<\/jats:italic>\n                  <jats:sub>phen<\/jats:sub>)-bidentate and an (<jats:italic>N<\/jats:italic>,<jats:italic>O<\/jats:italic>\n                  <jats:sub>phen<\/jats:sub>,<jats:italic>O<\/jats:italic>\n                  <jats:sub>alc<\/jats:sub>)-tridentate fashion in the case of the imino and amino forms, respectively. The shape of the CuN<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> coordination polyhedron is a distorted square-pyramid (geometry index \u03c4<jats:sub>5<\/jats:sub> = 0.26). Intermolecular N\u2014H...O and O\u2014H...O hydrogen bonds, involving H atoms of the amino and hydroxyethyl groups, create a two-dimensional supramolecular array extending parallel to (010).<\/jats:p>","DOI":"10.1107\/s205698902101166x","type":"journal-article","created":{"date-parts":[[2021,11,9]],"date-time":"2021-11-09T10:55:34Z","timestamp":1636455334000},"page":"1272-1275","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["A bis-chelate <i>o<\/i>-vanillin-2-ethanolamine copper(II) complex bearing both imine and amine forms of the ligand"],"prefix":"10.1107","volume":"77","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1835-5956","authenticated-orcid":true,"given":"Nataliya","family":"Plyuta","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1834-3020","authenticated-orcid":true,"given":"Vladimir N.","family":"Kokozay","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0801-1690","authenticated-orcid":true,"given":"Julia A.","family":"Rusanova","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3356-688X","authenticated-orcid":true,"given":"Halyna","family":"Buvailo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4675-2190","authenticated-orcid":true,"given":"Evgeny","family":"Goreshnik","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8594-2643","authenticated-orcid":true,"given":"Svitlana","family":"Petrusenko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2021,11,9]]},"reference":[{"key":"wm5622_bb1","doi-asserted-by":"crossref","first-page":"212","DOI":"10.1016\/j.jorganchem.2013.10.019","volume":"760","author":"Ad\u00e3o","year":"2014","journal-title":"J. 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