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The fluorenonophane contains two fluorenone fragments linked by two<jats:italic>m<\/jats:italic>-substituted benzene fragments. Some decrease in its macrocyclic cavity leads to a stacking interaction between the tricyclic fluorenone fragments. In the crystal, the fluorenonophane and chlorobenzene molecules are linked by weak C\u2014H...\u03c0(ring) interactions and C\u2014H...Cl hydrogen bonds. The Cl atom of chlorobenzene does not form a halogen bond. A Hirshfeld surface analysis and two-dimensional fingerprint plots were used to analyse the intermolecular contacts found in the crystal structure.<\/jats:p>","DOI":"10.1107\/s2056989021011865","type":"journal-article","created":{"date-parts":[[2021,11,11]],"date-time":"2021-11-11T12:31:02Z","timestamp":1636633862000},"page":"1285-1288","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Fluorenonophane chlorobenzene solvate: molecular and crystal structures"],"prefix":"10.1107","volume":"77","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4613-172X","authenticated-orcid":true,"given":"Viktoriya V.","family":"Dyakonenko","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3946-1061","authenticated-orcid":true,"given":"Svitlana V.","family":"Shishkina","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tatiana Yu.","family":"Bogashchenko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7538-303X","authenticated-orcid":true,"given":"Alexander Yu.","family":"Lyapunov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tatiana I.","family":"Kirichenko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2021,11,12]]},"reference":[{"key":"mw2179_bb1","doi-asserted-by":"crossref","first-page":"183","DOI":"10.1021\/ja307360n","volume":"135","author":"Barnes","year":"2013","journal-title":"J. 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