{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:27Z","timestamp":1740174567022,"version":"3.37.3"},"reference-count":36,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2021,11,18]],"date-time":"2021-11-18T00:00:00Z","timestamp":1637193600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2021,11,18]],"date-time":"2021-11-18T00:00:00Z","timestamp":1637193600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"National Science Foundation, Division of Materials Research","award":["CHE 1625543"],"award-info":[{"award-number":["CHE 1625543"]}]},{"DOI":"10.13039\/100018227","name":"National Research Foundation of Ukraine","doi-asserted-by":"crossref","award":["2020.02\/0202"],"award-info":[{"award-number":["2020.02\/0202"]}],"id":[{"id":"10.13039\/100018227","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2021,11,9]]},"published-print":{"date-parts":[[2021,12,1]]},"abstract":"<jats:p>The core of the title complex, bis[hexaaquahemiaquapentakis(\u03bc<jats:sub>3<\/jats:sub>-glycinehydroxamato)sulfatopentacopper(II)terbium(III)] sulfate hexahydrate, [TbCu<jats:sub>5<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(GlyHA)<jats:sub>5<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>6.5<\/jats:sub>]<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)\u00b76H<jats:sub>2<\/jats:sub>O (<jats:bold>1<\/jats:bold>), which belongs to the 15-metallacrown-5 family, consists of five glycinehydroxamate dianions (GlyHA<jats:sup>2\u2212<\/jats:sup>; C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>) and five copper(II) ions linked together forming a metallamacrocyclic moiety. The terbium(III) ion is connected to the centre of the metallamacrocycle through five hydroxamate oxygen atoms. The coordination environment of the Tb<jats:sup>3+<\/jats:sup> ion is completed to an octacoordination level by oxygen atoms of a bidentate sulfate and an apically coordinated water molecule, while the copper(II) atoms are square-planar, penta- or hexacoordinate due to the apical coordination of water molecules. Continuous shape calculations indicate that the coordination polyhedron of the Tb<jats:sup>3+<\/jats:sup> ion in <jats:bold>1<\/jats:bold> is best described as square antiprismatic. The positive charge of each pair of [TbCu<jats:sub>5<\/jats:sub>(GlyHA)<jats:sub>5<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>6.5<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)]<jats:sub>2<\/jats:sub>\n                  <jats:sup>2+<\/jats:sup> fragments is compensated by a non-coordinated sulfate anion, which is located on an inversion center with 1:1 disordered oxygen atoms. Complex <jats:bold>1<\/jats:bold> is isomorphous with the previously reported compounds [<jats:italic>Ln<\/jats:italic>Cu<jats:sub>5<\/jats:sub>(GlyHA)<jats:sub>5<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>6.5<\/jats:sub>]<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>), where <jats:italic>Ln<\/jats:italic>\n                  <jats:sup>III<\/jats:sup> = Pr, Nd, Sm, Eu, Gd, Dy and Ho.<\/jats:p>","DOI":"10.1107\/s2056989021011907","type":"journal-article","created":{"date-parts":[[2021,11,18]],"date-time":"2021-11-18T14:51:09Z","timestamp":1637247069000},"page":"1197-1202","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of a Tb<sup>III<\/sup>\u2013Cu<sup>II<\/sup> glycinehydroxamate 15-metallacrown-5 sulfate complex"],"prefix":"10.1107","volume":"77","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6625-6744","authenticated-orcid":true,"given":"Anna V.","family":"Pavlishchuk","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Inna V.","family":"Vasylenko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3305-852X","authenticated-orcid":true,"given":"Matthias","family":"Zeller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0706-7377","authenticated-orcid":true,"given":"Anthony W.","family":"Addison","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2021,11,18]]},"reference":[{"key":"yy2004_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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