{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T05:55:13Z","timestamp":1790834113456,"version":"4.1.0"},"reference-count":28,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2022,1,1]],"date-time":"2022-01-01T00:00:00Z","timestamp":1640995200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,1,1]],"date-time":"2022-01-01T00:00:00Z","timestamp":1640995200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2021,11,25]]},"published-print":{"date-parts":[[2022,1,1]]},"abstract":"<jats:p>A dicationic Pd<jats:sup>II<\/jats:sup> dimer, bis{2-[(diisopropylphosphanyl)methyl]quinoline-8-thiolato}palladium(II) bis(hexafluoridoantimonate) dichloromethane monosolvate, [Pd<jats:sub>2<\/jats:sub>(C<jats:sub>32<\/jats:sub>H<jats:sub>42<\/jats:sub>N<jats:sub>2<\/jats:sub>P<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>)](SbF<jats:sub>6<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, containing a 2-[(diisopropylphosphanyl)methyl]quinoline-8-thiolate pincer ligand, was isolated and its crystal structure determined. The title compound crystallizes in the orthorhombic space group <jats:italic>Pbca<\/jats:italic>. A dimeric structure is formed by bridging coordination of the S atoms. The geometry of the butterfly-shaped Pd<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub> core is bent, with a hinge angle of 108.0\u2005(1)\u00b0 and a short Pd...Pd distance of 2.8425\u2005(7)\u2005\u00c5. These values are the lowest measured compared to ten dicationic dimers with a Pd<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub> core featuring sulfur atoms embedded in a chelating ligand. One of the two hexafluoridoantimonate anions is disordered over two sets of positions with site-occupancy factors of 0.711\u2005(5) and 0.289\u2005(5). The crystal structure is stabilized by many C\u2014H...F and C\u2014H...\u03c0 interactions, forming a supramolecular network.<\/jats:p>","DOI":"10.1107\/s2056989021012561","type":"journal-article","created":{"date-parts":[[2021,12,2]],"date-time":"2021-12-02T14:37:26Z","timestamp":1638455846000},"page":"18-22","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure of a dicationic Pd<sup>II<\/sup> dimer containing a 2-[(diisopropylphosphanyl)methyl]quinoline-8-thiolate pincer ligand"],"prefix":"10.1107","volume":"78","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0875-968X","authenticated-orcid":true,"given":"Arnaud","family":"Clerc","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nathalie","family":"Saffon-Merceron","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Julien","family":"Monot","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Blanca","family":"Martin Vaca","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Didier","family":"Bourissou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2022,1,1]]},"reference":[{"key":"zq2270_bb1","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/S0020-1693(97)05589-8","volume":"264","author":"Albinati","year":"1997","journal-title":"Inorg. 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