{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,2]],"date-time":"2026-04-02T09:34:16Z","timestamp":1775122456505,"version":"3.50.1"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2022,1,25]],"date-time":"2022-01-25T00:00:00Z","timestamp":1643068800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,1,25]],"date-time":"2022-01-25T00:00:00Z","timestamp":1643068800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"publisher","award":["19BF037-01M"],"award-info":[{"award-number":["19BF037-01M"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010665","name":"H2020 Marie Sk\u0142odowska-Curie Actions","doi-asserted-by":"publisher","award":["734322"],"award-info":[{"award-number":["734322"]}],"id":[{"id":"10.13039\/100010665","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Yukhymenko Family Endowment Fund"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2022,1,17]]},"published-print":{"date-parts":[[2022,2,1]]},"abstract":"<jats:p>In the title polymeric coordination compound, {[FePt(CN)<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]\u00b71.33CH<jats:sub>3<\/jats:sub>OH}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, the Fe<jats:sup>II<\/jats:sup> cation (site symmetry 4\/<jats:italic>mm.m<\/jats:italic>) is coordinated by the N atoms of four cyanide anions (CN<jats:sup>\u2212<\/jats:sup>) and the O atoms of two water molecules, forming a nearly regular [FeN<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>] octahedron. According the Fe\u2014N and Fe\u2014O bond lengths, the Fe<jats:sup>II<\/jats:sup> atom is in the high-spin state. The cyanide anions act in a bridging manner to connect the Fe<jats:sup>II<\/jats:sup> and Pt<jats:sup>II<\/jats:sup> atoms. The [Pt(CN)<jats:sub>4<\/jats:sub>]<jats:sup>2\u2013<\/jats:sup> moieties (Pt with site symmetry 4\/<jats:italic>mm.m<\/jats:italic>) have a perfect square-planar shape. The latter anion is located perpendicular to the FeN<jats:sub>4<\/jats:sub> plane, thus ensuring the creation of a three-dimensional framework. The crystal structure features methanol solvent molecules of which 4\/3 were located per Fe<jats:sup>II<\/jats:sup> cation. These solvent molecules are located in hexagonal pores; they interact with coordinating water molecules through weak hydrogen bonds. Other guest molecules could not be modelled in a satisfactory way and their contribution to the scattering was removed by a mask procedure.<\/jats:p>","DOI":"10.1107\/s2056989022000573","type":"journal-article","created":{"date-parts":[[2022,1,25]],"date-time":"2022-01-25T09:28:43Z","timestamp":1643102923000},"page":"216-219","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of poly[[diaquatetra-\u03bc<sub>2<\/sub>-cyanido-platinum(II)iron(II)] methanol 4\/3-solvate]: a three-dimensional Hofmann clathrate analogue"],"prefix":"10.1107","volume":"78","author":[{"given":"Volodymyr M.","family":"Hiiuk","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vasyl","family":"Mykhailovych","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1222-4373","authenticated-orcid":true,"given":"Sergiu","family":"Shova","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Irina A.","family":"Golenya","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Il'ya A.","family":"Gural'skiy","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,1,25]]},"reference":[{"key":"wm5624_bb11","doi-asserted-by":"crossref","first-page":"2068","DOI":"10.1016\/j.ccr.2011.02.004","volume":"255","author":"Carmen Mu\u00f1oz","year":"2011","journal-title":"Coord. Chem. Rev."},{"key":"wm5624_bb2","doi-asserted-by":"crossref","first-page":"1414","DOI":"10.3390\/molecules23061414","volume":"23","author":"Dacarro","year":"2018","journal-title":"Molecules"},{"key":"wm5624_bb3","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"wm5624_bb4","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"wm5624_bb5","doi-asserted-by":"crossref","first-page":"6017","DOI":"10.1039\/C6CC00056H","volume":"52","author":"Haraguchi","year":"2016","journal-title":"Chem. Commun."},{"key":"wm5624_bb6","doi-asserted-by":"crossref","first-page":"204","DOI":"10.1002\/zaac.18970150118","volume":"15","author":"Hofmann","year":"1897","journal-title":"Z. Anorg. Chem."},{"key":"wm5624_bb7","doi-asserted-by":"crossref","first-page":"120303","DOI":"10.1016\/j.ica.2021.120303","volume":"521","author":"Kucheriv","year":"2021","journal-title":"Inorg. Chim. Acta"},{"key":"wm5624_bb8","doi-asserted-by":"crossref","first-page":"4906","DOI":"10.1021\/acs.inorgchem.6b00446","volume":"55","author":"Kucheriv","year":"2016","journal-title":"Inorg. Chem."},{"key":"wm5624_bb9","doi-asserted-by":"crossref","first-page":"9250","DOI":"10.1039\/D1DT01544C","volume":"50","author":"Kuzevanova","year":"2021","journal-title":"Dalton Trans."},{"key":"wm5624_bb10","doi-asserted-by":"crossref","first-page":"1536","DOI":"10.1107\/S2056989019012945","volume":"75","author":"Kuzevanova","year":"2019","journal-title":"Acta Cryst. E"},{"key":"wm5624_bb12","doi-asserted-by":"crossref","first-page":"3838","DOI":"10.1021\/ic010259y","volume":"40","author":"Niel","year":"2001","journal-title":"Inorg. Chem."},{"key":"wm5624_bb13","unstructured":"Pi\u00f1eiro-L\u00f3pez, L., Valverde-Mu\u00f1oz, F. J., Seredyuk, M. & Znovjyak, K. (2017). IUCrData, 2, x171413."},{"key":"wm5624_bb14","doi-asserted-by":"crossref","first-page":"566","DOI":"10.1038\/163566a0","volume":"163","author":"Powell","year":"1949","journal-title":"Nature"},{"key":"wm5624_bb15","unstructured":"Rigaku OD (2021). CrysAlis PRO. Rigaku Oxford Diffraction, Yarnton, England."},{"key":"wm5624_bb16","doi-asserted-by":"crossref","first-page":"7886","DOI":"10.1021\/ic500323r","volume":"53","author":"Sciortino","year":"2014","journal-title":"Inorg. Chem."},{"key":"wm5624_bb17","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"wm5624_bb18","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"wm5624_bb19","doi-asserted-by":"crossref","first-page":"6541","DOI":"10.1021\/acs.inorgchem.0c00627","volume":"59","author":"Shylin","year":"2020","journal-title":"Inorg. Chem."},{"key":"wm5624_bb1","doi-asserted-by":"crossref","first-page":"12986","DOI":"10.1021\/acsami.9b00693","volume":"11","author":"Wong","year":"2019","journal-title":"Appl. Mater. Interfaces"},{"key":"wm5624_bb20","doi-asserted-by":"crossref","first-page":"217","DOI":"10.1016\/S0020-1693(96)05484-9","volume":"257","author":"Yuge","year":"1997","journal-title":"Inorg. Chim. Acta"},{"key":"wm5624_bb21","doi-asserted-by":"crossref","first-page":"328","DOI":"10.1016\/j.ccr.2017.09.014","volume":"352","author":"Zakaria","year":"2017","journal-title":"Coord. Chem. Rev."},{"key":"wm5624_bb22","doi-asserted-by":"crossref","first-page":"1007","DOI":"10.1002\/zaac.201300352","volume":"640","author":"Zhang","year":"2014","journal-title":"Z. Anorg. Allg. Chem."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2022\/02\/00\/wm5624\/wm5624.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2022\/02\/00\/wm5624\/wm5624.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:49:18Z","timestamp":1736765358000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989022000573"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,1,25]]},"references-count":22,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2022,2]]}},"alternative-id":["S2056989022000573"],"URL":"https:\/\/doi.org\/10.1107\/s2056989022000573","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989022000573\/wm5624sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989022000573\/wm5624Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"value":"2056-9890","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,1,25]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?wm5624","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"14 October 2021","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"17 January 2022","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"25 January 2022","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5624"}},{"value":"\u00a9 2022 Hiiuk et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}