{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:29Z","timestamp":1740174569533,"version":"3.37.3"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2022,2,10]],"date-time":"2022-02-10T00:00:00Z","timestamp":1644451200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,2,10]],"date-time":"2022-02-10T00:00:00Z","timestamp":1644451200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/100000086","name":"National Science Foundation, Directorate for Mathematical and Physical Sciences","doi-asserted-by":"publisher","award":["CHE-0619278"],"award-info":[{"award-number":["CHE-0619278"]}],"id":[{"id":"10.13039\/100000086","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2022,2,7]]},"published-print":{"date-parts":[[2022,3,1]]},"abstract":"<jats:p>A new metal\u2013organic precursor for the chemical vapor deposition of zinc oxide thin films, [Zn(C<jats:sub>9<\/jats:sub>H<jats:sub>16<\/jats:sub>NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>], has been synthesized and characterized by <jats:sup>1<\/jats:sup>H and <jats:sup>13<\/jats:sup>C NMR spectroscopy, single-crystal X-ray diffraction and thermogravimetric analysis. The asymmetric unit of the title compound consists of two molecules (<jats:italic>Z<\/jats:italic>\u2032 = 2), with different zinc coordination polyhedra. In one molecule, the metal atom is in a distorted trigonal\u2013bipyramidal ZnN<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> environment (\u03c4<jats:sub>5<\/jats:sub> = 0.192) with a long bond to an ether O donor atom [Zn\u2014O = 2.727\u2005(6)\u2005\u00c5]. In the other, the Zn atom is in a distorted ZnN<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub> octahedral environment with long bonds to the ether O donors of both ligands [Zn\u2014O = 2.514\u2005(4) and 2.661\u2005(4)\u2005\u00c5; O\u2014Zn\u2014O = 82.46\u2005(14)\u00b0]. The crystal structure features weak C\u2014H...\u00b7O interactions.<\/jats:p>","DOI":"10.1107\/s2056989022001475","type":"journal-article","created":{"date-parts":[[2022,2,10]],"date-time":"2022-02-10T11:37:36Z","timestamp":1644493056000},"page":"317-321","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Distorted zinc coordination polyhedra in bis(1-ethoxy-2-{[(2-methoxyethyl)imino]methyl}propan-1-olato)zinc, a possible CVD precursor for zinc oxide thin films"],"prefix":"10.1107","volume":"78","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8176-2098","authenticated-orcid":true,"given":"Keneshia O.","family":"Johnson","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Antionette","family":"Brown","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gabriella","family":"Farris","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexabria","family":"Starks","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2770-7076","authenticated-orcid":true,"given":"Ray J.","family":"Butcher","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jason S.","family":"Matthews","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,2,10]]},"reference":[{"key":"hb8009_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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