{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,7]],"date-time":"2026-01-07T07:35:13Z","timestamp":1767771313650,"version":"3.37.3"},"reference-count":31,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2022,2,15]],"date-time":"2022-02-15T00:00:00Z","timestamp":1644883200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,2,15]],"date-time":"2022-02-15T00:00:00Z","timestamp":1644883200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"JSPS KAKENHI","award":["JP20K05565"],"award-info":[{"award-number":["JP20K05565"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2022,2,9]]},"published-print":{"date-parts":[[2022,3,1]]},"abstract":"<jats:p>In the title compound, [ZnBr<jats:sub>2<\/jats:sub>(C<jats:sub>22<\/jats:sub>H<jats:sub>19<\/jats:sub>ClN<jats:sub>4<\/jats:sub>O)], the Zn<jats:sup>II<\/jats:sup> atom adopts a distorted square-pyramidal coordination geometry, formed by two bromido ligands and three N atoms of the bis(pyridin-2-ylmethyl)amine moiety in the pentadentate ligand containing quinolinol. The Zn<jats:sup>II<\/jats:sup> atom is located well above the mean basal plane of the square-based pyramid. The apical position is occupied by a Br atom. The O and N atoms of the quinolinol moiety in the ligand are not coordinated to the Zn<jats:sup>II<\/jats:sup> atom. An intramolecular O\u2014H...N hydrogen bond, generating an <jats:italic>S<\/jats:italic>(5) ring motif, stabilizes the molecular structure. In the crystal, the molecules are linked by intermolecular C\u2014H...Br hydrogen bonds, generating ribbon structures containing alternating <jats:italic>R<\/jats:italic>\n                  <jats:sub>2<\/jats:sub>\n                  <jats:sup>2<\/jats:sup>(22) and <jats:italic>R<\/jats:italic>\n                  <jats:sub>2<\/jats:sub>\n                  <jats:sup>2<\/jats:sup>(14) rings. These ribbons are linked through an intermolecular C\u2014H...Br hydrogen bond, forming a two-dimensional network sheet.<\/jats:p>","DOI":"10.1107\/s2056989022001530","type":"journal-article","created":{"date-parts":[[2022,2,15]],"date-time":"2022-02-15T09:34:10Z","timestamp":1644917650000},"page":"326-329","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structure of (7-{[bis(pyridin-2-ylmethyl)amino-\u03ba<sup>3<\/sup>\n                  <i>N<\/i>,<i>N<\/i>\u2032,<i>N<\/i>\u2032\u2032]methyl}-5-chloroquinolin-8-ol)dibromidozinc(II)"],"prefix":"10.1107","volume":"78","author":[{"given":"Koji","family":"Kubono","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4122-3345","authenticated-orcid":true,"given":"Yukiyasu","family":"Kashiwagi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Keita","family":"Tani","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kunihiko","family":"Yokoi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,2,15]]},"reference":[{"key":"yz2016_bb1","doi-asserted-by":"crossref","first-page":"2207","DOI":"10.1021\/ic00112a038","volume":"34","author":"Abufarag","year":"1995","journal-title":"Inorg. Chem."},{"key":"yz2016_bb2","doi-asserted-by":"crossref","first-page":"4785","DOI":"10.1039\/D0DT00315H","volume":"49","author":"Acharya","year":"2020","journal-title":"Dalton Trans."},{"key":"yz2016_bb3","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"yz2016_bb4","doi-asserted-by":"crossref","first-page":"343","DOI":"10.1107\/S0021889892010331","volume":"26","author":"Altomare","year":"1993","journal-title":"J. Appl. Cryst."},{"key":"yz2016_bb5","doi-asserted-by":"crossref","first-page":"15299","DOI":"10.1039\/D0RA01455A","volume":"10","author":"Aoki","year":"2020","journal-title":"RSC Adv."},{"key":"yz2016_bb6","doi-asserted-by":"crossref","first-page":"7739","DOI":"10.1021\/acs.inorgchem.0c00777","volume":"59","author":"Bazany-Rodr\u00edguez","year":"2020","journal-title":"Inorg. Chem."},{"key":"yz2016_bb7","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1107\/S0108768102003324","volume":"58","author":"Bruno","year":"2002","journal-title":"Acta Cryst. B"},{"key":"yz2016_bb8","doi-asserted-by":"crossref","first-page":"1003","DOI":"10.2116\/analsci.19P132","volume":"35","author":"Eguchi","year":"2019","journal-title":"Anal. Sci."},{"key":"yz2016_bb9","doi-asserted-by":"crossref","first-page":"12220","DOI":"10.1039\/c2dt31306e","volume":"41","author":"Gao","year":"2012","journal-title":"Dalton Trans."},{"key":"yz2016_bb10","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"yz2016_bb11","unstructured":"Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan."},{"key":"yz2016_bb20","doi-asserted-by":"crossref","first-page":"2440","DOI":"10.1021\/acs.cgd.9b01625","volume":"20","author":"Juraj","year":"2020","journal-title":"Cryst. Growth Des."},{"key":"yz2016_bb12","doi-asserted-by":"crossref","first-page":"1545","DOI":"10.1107\/S2056989015022410","volume":"71","author":"Kubono","year":"2015","journal-title":"Acta Cryst. E"},{"key":"yz2016_bb13","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1016\/j.abb.2009.09.008","volume":"491","author":"Lai","year":"2009","journal-title":"Arch. Biochem. Biophys."},{"key":"yz2016_bb14","doi-asserted-by":"crossref","first-page":"2564","DOI":"10.1016\/j.poly.2011.07.003","volume":"30","author":"Lamsh\u00f6ft","year":"2011","journal-title":"Polyhedron"},{"key":"yz2016_bb15","doi-asserted-by":"crossref","first-page":"32490","DOI":"10.1039\/D0RA05168C","volume":"10","author":"Li","year":"2020","journal-title":"RSC Adv."},{"key":"yz2016_bb16","doi-asserted-by":"crossref","first-page":"13512","DOI":"10.1021\/ja4059487","volume":"135","author":"Lin","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"yz2016_bb17","doi-asserted-by":"crossref","first-page":"1937","DOI":"10.1016\/j.ica.2007.10.004","volume":"361","author":"McDonald","year":"2008","journal-title":"Inorg. Chim. Acta"},{"key":"yz2016_bb18","doi-asserted-by":"crossref","first-page":"632","DOI":"10.1021\/ac60162a017","volume":"32","author":"Medlin","year":"1960","journal-title":"Anal. Chem."},{"key":"yz2016_bb19","doi-asserted-by":"crossref","first-page":"m1282","DOI":"10.1107\/S1600536811032351","volume":"67","author":"Najafi","year":"2011","journal-title":"Acta Cryst. E"},{"key":"yz2016_bb21","doi-asserted-by":"crossref","first-page":"4054","DOI":"10.1021\/om9602771","volume":"15","author":"Plenio","year":"1996","journal-title":"Organometallics"},{"key":"yz2016_bb22","unstructured":"Rigaku (2006). RAPID-AUTO. Rigaku Corporation, Tokyo, Japan."},{"key":"yz2016_bb23","unstructured":"Rigaku (2016). CrystalStructure. Rigaku Corporation, Tokyo, Japan."},{"key":"yz2016_bb24","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1016\/j.poly.2012.11.027","volume":"58","author":"Royzen","year":"2013","journal-title":"Polyhedron"},{"key":"yz2016_bb25","doi-asserted-by":"crossref","first-page":"3854","DOI":"10.1021\/ja056631g","volume":"128","author":"Royzen","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"yz2016_bb26","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"yz2016_bb27","doi-asserted-by":"crossref","first-page":"204","DOI":"10.1016\/j.ica.2019.02.029","volume":"489","author":"Singh","year":"2019","journal-title":"Inorg. Chim. Acta"},{"key":"yz2016_bb28","doi-asserted-by":"crossref","first-page":"2845","DOI":"10.1039\/C5DT03387J","volume":"45","author":"\u0160kalamera","year":"2016","journal-title":"Dalton Trans."},{"key":"yz2016_bb29","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1107\/S2056989019016244","volume":"76","author":"Spek","year":"2020","journal-title":"Acta Cryst. E"},{"key":"yz2016_bb30","doi-asserted-by":"crossref","first-page":"4310","DOI":"10.1021\/ic702393z","volume":"47","author":"Xue","year":"2008","journal-title":"Inorg. Chem."},{"key":"yz2016_bb31","doi-asserted-by":"crossref","first-page":"7513","DOI":"10.1039\/C6NJ00346J","volume":"40","author":"Zhang","year":"2016","journal-title":"New J. Chem."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2022\/03\/00\/yz2016\/yz2016.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2022\/03\/00\/yz2016\/yz2016.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:53:23Z","timestamp":1736765603000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989022001530"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,2,15]]},"references-count":31,"journal-issue":{"issue":"3","published-online":{"date-parts":[[2022,3]]}},"alternative-id":["S2056989022001530"],"URL":"https:\/\/doi.org\/10.1107\/s2056989022001530","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2056989022001530\/yz2016sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2056989022001530\/yz2016Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2022,2,15]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"research communications","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?yz2016","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"18 January 2022","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"9 February 2022","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"15 February 2022","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?yz2016"}},{"value":"\u00a9 2022 Kubono et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}