{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:31Z","timestamp":1740174571122,"version":"3.37.3"},"reference-count":38,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2022,4,12]],"date-time":"2022-04-12T00:00:00Z","timestamp":1649721600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,4,12]],"date-time":"2022-04-12T00:00:00Z","timestamp":1649721600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2022,4,5]]},"published-print":{"date-parts":[[2022,5,1]]},"abstract":"<jats:p>Reaction of Zn(ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b76H<jats:sub>2<\/jats:sub>O with cyclam (cyclam = 1,4,8,11-tetraazacyclotetradecane, C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>) and Na<jats:sub>3<\/jats:sub>SbS<jats:sub>4<\/jats:sub> in an acetonitrile\/water mixture led to the formation of crystals of the title compound, [Zn<jats:sub>3<\/jats:sub>(SbS<jats:sub>4<\/jats:sub>)(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>](SbS<jats:sub>4<\/jats:sub>)\u00b72CH<jats:sub>3<\/jats:sub>CN\u00b72H<jats:sub>2<\/jats:sub>O or [(Zn-cyclam)<jats:sub>3<\/jats:sub>(SbS<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>](H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>(acetonitrile)<jats:sub>2<\/jats:sub>. The set-up of the crystal structure is similar to that of [(Zn-cyclam)<jats:sub>3<\/jats:sub>(SbS<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sup>.<\/jats:sup>8H<jats:sub>2<\/jats:sub>O reported recently [Danker <jats:italic>et al.<\/jats:italic> (2021). <jats:italic>Dalton Trans<\/jats:italic>. <jats:bold>50<\/jats:bold>, 18107\u201318117]. The crystal structure of the title compound consists of three crystallographically independent Zn<jats:sup>II<\/jats:sup> cations (each disordered around centers of inversion), three centrosymmetric cyclam ligands, one SbS<jats:sub>4<\/jats:sub>\n                  <jats:sup>3\u2013<\/jats:sup> anion, one water and one acetonitrile molecule occupying general positions. The acetonitrile molecule is equally disordered over two sets of sites. Each Zn<jats:sup>2+<\/jats:sup> cation is bound to four nitrogen atoms of a cyclam ligand and one sulfur atom of the SbS<jats:sub>4<\/jats:sub>\n                  <jats:sup>3\u2013<\/jats:sup> anion within a distorted square-pyramidal coordination. The cation disorder of the [Zn(cyclam)]<jats:sup>2+<\/jats:sup> complexes is discussed in detail and is also observed in other compounds, where identical ligands are located above and below the [Zn(cyclam)]<jats:sup>2+<\/jats:sup> plane. In the title compound, the building units are arranged in layers parallel to the <jats:italic>bc<\/jats:italic> plane forming pores in which the acetonitrile solvate molecules are located. Intermolecular C\u2014H...S hydrogen bonding links these units to the SbS<jats:sub>4<\/jats:sub>\n                  <jats:sup>3\u2013<\/jats:sup> anions. Between the layers, additional water solvate molecules are present that act as acceptor and donor groups for intermolecular N\u2014H...O and O\u2014H...S hydrogen bonding.<\/jats:p>","DOI":"10.1107\/s2056989022003759","type":"journal-article","created":{"date-parts":[[2022,4,12]],"date-time":"2022-04-12T08:41:28Z","timestamp":1649752888000},"page":"490-495","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structure of \u03bc<sub>3<\/sub>-tetrathioantimonato-tris[(cyclam)zinc(II)] tetrathioantimonate acetonitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetraazacyclotetradecane)"],"prefix":"10.1107","volume":"78","author":[{"given":"Christian","family":"N\u00e4ther","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Felix","family":"Danker","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3111-580X","authenticated-orcid":true,"given":"Wolfgang","family":"Bensch","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,4,12]]},"reference":[{"key":"wm5639_bb1","doi-asserted-by":"crossref","first-page":"3802","DOI":"10.1021\/acs.cgd.6b00356","volume":"16","author":"Anderer","year":"2016","journal-title":"Cryst. 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