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The 1,3-oxazolidine ring adopts an envelope conformation with the N atom in an <jats:italic>endo<\/jats:italic> position. The mean plane of the oxazolidine ring makes dihedral angles of 77.74\u2005(10) and 45.50\u2005(11)\u00b0, respectively, with the 4-bromophenol and 1,3,5-trimethylbenzene rings. In the crystal, adjacent molecules are connected <jats:italic>via<\/jats:italic> C\u2014H...O hydrogen bonds and C\u2014H...\u03c0 interactions into layers parallel to the (200) plane. The packing is strengthened by van der Waals interactions between parallel molecular layers. A Hirshfeld surface analysis shows that H...H (58.2%), C...H\/H...C (18.9%), and Br...H\/H...Br (11.5%) interactions are the most abundant in the crystal packing.<\/jats:p>","DOI":"10.1107\/s2056989022005928","type":"journal-article","created":{"date-parts":[[2022,6,10]],"date-time":"2022-06-10T05:06:53Z","timestamp":1654837613000},"page":"695-698","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure and Hirshfeld surface analysis of 4-bromo-2-[3-methyl-5-(2,4,6-trimethylbenzyl)oxazolidin-2-yl]phenol"],"prefix":"10.1107","volume":"78","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5219-2986","authenticated-orcid":true,"given":"Ali N.","family":"Khalilov","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Victor N.","family":"Khrustalev","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Elena A.","family":"Fortalnova","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2421-0929","authenticated-orcid":true,"given":"Mehmet","family":"Akkurt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sema \u00d6zt\u00fcrk","family":"Y\u0131ld\u0131r\u0131m","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ajaya","family":"Bhattarai","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"\u0130brahim G.","family":"Mamedov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,6,10]]},"reference":[{"key":"tx2051_bb1","doi-asserted-by":"crossref","first-page":"o2755","DOI":"10.1107\/S160053681103858X","volume":"67","author":"Caracelli","year":"2011","journal-title":"Acta Cryst. 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