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IR spectroscopic investigations indicate that only terminally coordinated thiocyanate anions are present. This is confirmed by single-crystal structure analysis, which shows that their crystal structures consist of discrete centrosymmetric complexes, in which the metal cations are octahedrally coordinated by two N-bonded thiocyanate anions and four 3-methylpyridine ligands. X-ray powder diffraction (XRPD) proves that pure samples have been obtained. Thermogravimetric measurements show that decomposition starts at about 90\u00b0C and that the two coligands are removed in one step for <jats:bold>1<\/jats:bold> whereas for <jats:bold>2<\/jats:bold> no clearly resolved steps are visible. XRPD measurements of the residue obtained after the first mass loss of <jats:bold>1<\/jats:bold> show that a new and unknown crystalline compound has been formed.<\/jats:p>","DOI":"10.1107\/s2056989022006491","type":"journal-article","created":{"date-parts":[[2022,6,30]],"date-time":"2022-06-30T08:17:17Z","timestamp":1656577037000},"page":"755-760","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Syntheses, crystal structures and properties of tetrakis(3-methylpyridine-\u03ba<i>N<\/i>)bis(isothiocyanato-\u03ba<i>N<\/i>)manganese(II) and tetrakis(3-methylpyridine-\u03ba<i>N<\/i>)bis(isothiocyanato-\u03ba<i>N<\/i>)iron(II)"],"prefix":"10.1107","volume":"78","author":[{"given":"Magdalena","family":"Ceglarska","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christoph","family":"Krebs","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christian","family":"N\u00e4ther","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,6,30]]},"reference":[{"key":"hb8024_bb1","doi-asserted-by":"crossref","first-page":"m994","DOI":"10.1107\/S1600536811024561","volume":"67","author":"Boeckmann","year":"2011","journal-title":"Acta Cryst. 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