{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:33Z","timestamp":1740174573662,"version":"3.37.3"},"reference-count":31,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2022,6,30]],"date-time":"2022-06-30T00:00:00Z","timestamp":1656547200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,6,30]],"date-time":"2022-06-30T00:00:00Z","timestamp":1656547200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2022,6,26]]},"published-print":{"date-parts":[[2022,7,1]]},"abstract":"<jats:p>The components of the title compound, [Ni(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub>[Ni(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)(C<jats:sub>27<\/jats:sub>H<jats:sub>24<\/jats:sub>O<jats:sub>9<\/jats:sub>P<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b710H<jats:sub>2<\/jats:sub>O are two centrosymmetric [Ni(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]<jats:sup>2+<\/jats:sup> dications, a centrosymmetric [Ni(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)(C<jats:sub>27<\/jats:sub>H<jats:sub>24<\/jats:sub>O<jats:sub>9<\/jats:sub>P<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sup>4\u2212<\/jats:sup> tetra-anion and five crystallographically unique water molecules of crystallization. All of the nickel ions are coordinated by the four secondary N atoms of the macrocyclic cyclam ligands, which adopt the most energetically stable <jats:italic>trans<\/jats:italic>-III conformation, and the mutually <jats:italic>trans<\/jats:italic> O atoms of either water molecules in the cations or the phosphonate groups in the anion in a tetragonally distorted NiN<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub> octahedral coordination geometry. Strong O\u2014H...O hydrogen bonds between the protonated and the non-protonated phosphonate O atoms of neighboring anions result in the formation of layers oriented parallel to the <jats:italic>bc<\/jats:italic> plane, which are linked into a three-dimensional network by virtue of numerous N\u2014H...O and O\u2014H...O hydrogen bonds arising from the <jats:italic>sec<\/jats:italic>-NH groups of the macrocycles, phosphonate O atoms and coordinated and non-coordinated water molecules.<\/jats:p>","DOI":"10.1107\/s2056989022006624","type":"journal-article","created":{"date-parts":[[2022,6,30]],"date-time":"2022-06-30T08:17:17Z","timestamp":1656577037000},"page":"750-754","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystal structure of bis[<i>trans<\/i>-diaqua(1,4,8,11-tetraazacyclotetradecane-\u03ba<sup>4<\/sup>\n                  <i>N<\/i>\n                  <sup>1<\/sup>,<i>N<\/i>\n                  <sup>4<\/sup>,<i>N<\/i>\n                  <sup>8<\/sup>,<i>N<\/i>\n                  <sup>11<\/sup>)nickel(II)] <i>trans<\/i>-(1,4,8,11-tetraazacyclotetradecane-\u03ba<sup>4<\/sup>\n                  <i>N<\/i>\n                  <sup>1<\/sup>,<i>N<\/i>\n                  <sup>4<\/sup>,<i>N<\/i>\n                  <sup>8<\/sup>,<i>N<\/i>\n                  <sup>11<\/sup>)bis[4,4\u2032,4\u2032\u2032-(1,3,5-trimethylbenzene-2,4,6-triyl)tris(hydrogen phenylphosphonato-\u03ba<i>O<\/i>)]nickel(II) decahydrate"],"prefix":"10.1107","volume":"78","author":[{"given":"Liudmyla V.","family":"Tsymbal","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rodinel","family":"Ardeleanu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sergiu","family":"Shova","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3800-6697","authenticated-orcid":true,"given":"Yaroslaw D.","family":"Lampeka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,6,30]]},"reference":[{"key":"hb8026_bb1","doi-asserted-by":"crossref","first-page":"1993","DOI":"10.1039\/C7CE00313G","volume":"19","author":"Alexandrov","year":"2017","journal-title":"CrystEngComm"},{"key":"hb8026_bb2","doi-asserted-by":"crossref","first-page":"4197","DOI":"10.1021\/ic00243a028","volume":"25","author":"Barefield","year":"1986","journal-title":"Inorg. 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