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The dihedral angle between the planes of the aromatic rings is 73.6\u2005(1)\u00b0. The conformation of the molecule is stabilized by intramolecular O\u2014H...O (1.86\u20132.12\u2005\u00c5) and C\u2014H...N (2.40, 2.54\u2005\u00c5) hydrogen bonds. Dimers of inversion-related molecules represent the basic supramolecular entities of the crystal structure. They are further connected <jats:italic>via<\/jats:italic> O\u2014H...O hydrogen bonding into undulating layers extending parallel to the crystallographic <jats:italic>bc<\/jats:italic> plane. Interlayer interaction is accomplished by weak C\u2014H...\u03c0 contacts.<\/jats:p>","DOI":"10.1107\/s2056989022007411","type":"journal-article","created":{"date-parts":[[2022,7,26]],"date-time":"2022-07-26T08:16:42Z","timestamp":1658823402000},"page":"825-828","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Synthesis and crystal structure of 1,3-bis{[<i>N<\/i>,<i>N<\/i>-bis(2-hydroxyethyl)amino]methyl}-5-{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-triethylbenzene"],"prefix":"10.1107","volume":"78","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6398-2337","authenticated-orcid":true,"given":"Manuel","family":"Stapf","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ute","family":"Schmidt","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wilhelm","family":"Seichter","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Monika","family":"Mazik","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2022,7,26]]},"reference":[{"key":"jq2019_bb1","doi-asserted-by":"crossref","first-page":"10648","DOI":"10.1039\/C6OB01682K","volume":"14","author":"Amrhein","year":"2016","journal-title":"Org. 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