{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:34Z","timestamp":1740174574438,"version":"3.37.3"},"reference-count":36,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2022,8,18]],"date-time":"2022-08-18T00:00:00Z","timestamp":1660780800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,8,18]],"date-time":"2022-08-18T00:00:00Z","timestamp":1660780800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation, Major Research Instrumentation Program","doi-asserted-by":"publisher","award":["CHE 1625543"],"award-info":[{"award-number":["CHE 1625543"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Shippensburg University Student Faculty Research Engagement (SFRE) Program"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2022,8,8]]},"published-print":{"date-parts":[[2022,9,1]]},"abstract":"<jats:p>The synthesis and crystal structure for the title compound, hexaaquahexakis(\u03bc-2-hydroxybenzenecarbohydroxamato)bis(2-hydroxybenzenecarbohydroxamato)tetraindium(III) tetranitrate 8.57-hydrate + unknown solvent, [In<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>shi)<jats:sub>8<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>6<\/jats:sub>](NO<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>\u00b78.57H<jats:sub>2<\/jats:sub>O\u00b7solvent, where H<jats:sub>2<\/jats:sub>shi<jats:sup>\u2212<\/jats:sup> is salicylhydroximate (C<jats:sub>7<\/jats:sub>H<jats:sub>5<\/jats:sub>NO<jats:sub>3<\/jats:sub>), are reported. The complex cation of the structure, [In<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>shi)<jats:sub>8<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>6<\/jats:sub>]<jats:sup>4+<\/jats:sup>, is a dimer with a step-like topology and possesses an inversion center that relates each [In<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>shi)<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>3<\/jats:sub>]<jats:sup>2+<\/jats:sup> side of the complex cation. Each In<jats:sup>III<\/jats:sup> ion is seven-coordinate with a pentagonal\u2013bipyramidal geometry, and the salicylhydroximate ligands have a 1\u2212 charge as only the oxime oxygen of the ligand is deprotonated. Four interstitial nitrate anions maintain the charge balance of the compound. One of the nitrate anions (and its symmetry equivalent) is disordered over two different orientations with an occupancy ratio of 0.557\u2005(7) to 0.443\u2005(7). The interstitial solvent water molecules show substantial disorder. Approximately 8.57 water molecules per formula unit were refined as disordered and partially occupied, while a suitable model could not be devised for the other extensively disordered solvent molecules (water and possibly methanol as this was the synthesis solvent). Thus, these latter solvent molecules were instead treated with the SQUEEZE routine [Spek (2015). <jats:italic>Acta Cryst<\/jats:italic>. C<jats:bold>71<\/jats:bold>, 9\u201318.] as implemented in the program <jats:italic>PLATON<\/jats:italic>, and the procedure corrected for 151 electrons within solvent-accessible voids of 367\u2005\u00c5<jats:sup>3<\/jats:sup>.<\/jats:p>","DOI":"10.1107\/s2056989022007964","type":"journal-article","created":{"date-parts":[[2022,8,18]],"date-time":"2022-08-18T11:17:25Z","timestamp":1660821445000},"page":"926-931","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of an indium\u2013salicylhydroximate complex cation: [In<sub>4<\/sub>(H<sub>2<\/sub>shi)<sub>8<\/sub>(H<sub>2<\/sub>O)<sub>6<\/sub>](NO<sub>3<\/sub>)<sub>4<\/sub>\u00b78.57H<sub>2<\/sub>O"],"prefix":"10.1107","volume":"78","author":[{"given":"Ozha A.","family":"Aziz","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3305-852X","authenticated-orcid":true,"given":"Matthias","family":"Zeller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4831-2911","authenticated-orcid":true,"given":"Curtis M.","family":"Zaleski","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,8,18]]},"reference":[{"key":"mw2189_bb1","doi-asserted-by":"crossref","first-page":"1729","DOI":"10.1021\/ic402865p","volume":"53","author":"Azar","year":"2014","journal-title":"Inorg. 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