{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:49:35Z","timestamp":1740174575874,"version":"3.37.3"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2022,9,26]],"date-time":"2022-09-26T00:00:00Z","timestamp":1664150400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,9,26]],"date-time":"2022-09-26T00:00:00Z","timestamp":1664150400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"GVSU Office of Undergraduate Research","award":["MS3"],"award-info":[{"award-number":["MS3"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2022,9,16]]},"published-print":{"date-parts":[[2022,10,1]]},"abstract":"<jats:p>The crystal structure of the title compound, [AuCl(C<jats:sub>16<\/jats:sub>H<jats:sub>13<\/jats:sub>PS)], is reported. The molecular structure features a nearly linear arrangement of the chloride and phosphino ligands around the gold(I) center, with a P\u2014Au\u2014Cl bond angle of 179.42\u2005(9)\u00b0. The Au\u2014P and Au\u2014Cl bond lengths are 2.226\u2005(2) and 2.287\u2005(2)\u2005\u00c5, respectively. The geometry of the groups bonded to the phosphorus atom of the ligand is a slightly distorted tetrahedron. The phenyl and thienyl rings of the ligand are extensively disordered, with the thienyl refined over all three possible positions on the phosphorus atom. The relative occupancy ratio between these positions was found to be 0.406\u2005(3):0.406\u2005(2):0.188\u2005(2). One of the major thienyl ring positions with the relative occupancy of 0.406 was modeled as two rotational isomers around the C\u2014P bond with a relative occupancy ratio of 0.278\u2005(3):0.128\u2005(3). Intermolecular C\u2014H...\u03c0 interactions present in the crystal lattice link molecules of the title compound together to form a complex three-dimensional network.<\/jats:p>","DOI":"10.1107\/s2056989022009227","type":"journal-article","created":{"date-parts":[[2022,9,27]],"date-time":"2022-09-27T07:46:04Z","timestamp":1664264764000},"page":"1044-1047","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of chlorido[diphenyl(thiophen-2-yl)phosphine-\u03ba<i>P<\/i>]gold(I)"],"prefix":"10.1107","volume":"78","author":[{"given":"Thomas","family":"Neils","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrew","family":"LaDuca","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9684-3656","authenticated-orcid":true,"given":"John E.","family":"Bender","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2760-769X","authenticated-orcid":true,"given":"Richard J.","family":"Staples","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shannon M.","family":"Biros","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,9,26]]},"reference":[{"key":"zl5036_bb1","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1107\/S2053273314022207","volume":"71","author":"Bourhis","year":"2015","journal-title":"Acta Cryst. 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