{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T05:25:22Z","timestamp":1790141122728,"version":"4.0.1"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2022,10,13]],"date-time":"2022-10-13T00:00:00Z","timestamp":1665619200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2022,10,13]],"date-time":"2022-10-13T00:00:00Z","timestamp":1665619200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"accepted":{"date-parts":[[2022,10,9]]},"published-print":{"date-parts":[[2022,11,1]]},"abstract":"<jats:p>The asymmetric unit of <jats:italic>catena<\/jats:italic>-poly[[[(1,4,8,11-tetraazacyclotetradecane-\u03ba<jats:sup>4<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>4<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>8<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>11<\/jats:sup>)nickel(II)]-\u03bc<jats:sub>2<\/jats:sub>-5-carboxybenzene-1,3-dicarboxylato-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>O<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>3<\/jats:sup>] octahydrate], {[Ni(C<jats:sub>9<\/jats:sub>H<jats:sub>4<\/jats:sub>O<jats:sub>6<\/jats:sub>)(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)]\u00b78H<jats:sub>2<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>I<\/jats:bold>), consists of a macrocyclic Ni<jats:sup>2+<\/jats:sup> cation, a carboxylate dianion and eight highly disordered water molecules of crystallization. The components of the compound <jats:italic>catena<\/jats:italic>-poly[[[(1,4,8,11-tetraazacyclotetradecane-\u03ba<jats:sup>4<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>4<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>8<\/jats:sup>,<jats:italic>N<\/jats:italic>\n                  <jats:sup>11<\/jats:sup>)nickel(II)]-\u03bc<jats:sub>2<\/jats:sub>-5-carboxybenzene-1,3-dicarboxylato-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>O<\/jats:italic>\n                  <jats:sup>1<\/jats:sup>:<jats:italic>O<\/jats:italic>\n                  <jats:sup>3<\/jats:sup>] monohydrate], {[Ni(C<jats:sub>9<\/jats:sub>H<jats:sub>4<\/jats:sub>O<jats:sub>6<\/jats:sub>)(C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>)]\u00b7H<jats:sub>2<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>II<\/jats:bold>), are two crystallographically unique centrosymmetric macrocyclic dications, a carboxylate dianion and one water molecule of crystallization. In each compound, the metal ion is coordinated in the equatorial plane by the four secondary N atoms of the macrocyclic ligand, which adopts the most energetically stable <jats:italic>trans<\/jats:italic>-III conformation, and two mutually <jats:italic>trans<\/jats:italic> O atoms of the carboxylate anions in a slightly tetragonally distorted <jats:italic>trans<\/jats:italic>-NiN<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub> octahedral geometry. The crystals of both compounds are composed of parallel coordination polymeric chains running along the [010] direction in <jats:bold>I<\/jats:bold> and the [110] and [1\\overline{1}0] directions in <jats:bold>II<\/jats:bold>. The bridging carboxylate anions display different modes of coordination connected with the relative orientation of coordinated O atoms, <jats:italic>i.e.<\/jats:italic>, remote in <jats:bold>I<\/jats:bold> and intermediate in <jats:bold>II<\/jats:bold>, thus resulting in essentially different distances between the Ni atoms in the chains [11.0657\u2005(4) and 8.9089\u2005(2)\u2005\u00c5 in <jats:bold>I<\/jats:bold> and <jats:bold>II<\/jats:bold>, respectively]. As a result of hydrogen-bonding interactions, the chains are joined together in sheets oriented parallel to the (10\\overline{1}) and (001) planes in <jats:bold>I<\/jats:bold> and <jats:bold>II<\/jats:bold>, respectively.<\/jats:p>","DOI":"10.1107\/s2056989022009860","type":"journal-article","created":{"date-parts":[[2022,10,13]],"date-time":"2022-10-13T14:21:48Z","timestamp":1665670908000},"page":"1122-1126","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Syntheses and structural characterizations of the first coordination polymers assembled from the Ni(cyclam)<sup>2+<\/sup> cation and the benzene-1,3,5-tricarboxylate linker"],"prefix":"10.1107","volume":"78","author":[{"given":"Sergey P.","family":"Gavrish","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1222-4373","authenticated-orcid":true,"given":"Sergiu","family":"Shova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3800-6697","authenticated-orcid":true,"given":"Yaroslaw D.","family":"Lampeka","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2022,10,13]]},"reference":[{"key":"hb8040_bb1","doi-asserted-by":"crossref","first-page":"1109","DOI":"10.1021\/ic50030a004","volume":"4","author":"Bosnich","year":"1965","journal-title":"Inorg. 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